TDPAC and β-NMR applications in chemistry and biochemistry

Attila Jancso; Joao G. Correia; Alexander  Gottberg; Juliana  Schell; Monika  Stachura; Daniel Mihaly Szunyogh; Stavroula Pallada; Doru C. Lupascu; Magdalena Kowalska; Lars Bo Stegeager Hemmingsen

doi:10.1088/1361-6471/aa666b

TDPAC and β-NMR applications in chemistry and biochemistry

Attila Jancso, Joao G. Correia, Alexander Gottberg, Juliana Schell, Monika Stachura, Daniel Mihaly Szunyogh, Stavroula Pallada, Doru C. Lupascu, Magdalena Kowalska, Lars Bo Stegeager Hemmingsen

Department of Chemistry

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Abstract

Time differential perturbed angular correlation (TDPAC) of γ-rays spectroscopy has been applied in chemistry and biochemistry for decades. Herein we aim to present a comprehensive review of chemical and biochemical applications of TDPAC spectroscopy conducted at ISOLDE over the past 15 years, including elucidation of metal site structure and dynamics in proteins and model systems. β-NMR spectroscopy is well established in nuclear physics, solid state physics, and materials science, but only a limited number of applications in chemistry have appeared. Current endeavors at ISOLDE advancing applications of β-NMR towards chemistry and biochemistry are presented, including the first experiment on ³¹Mg²⁺ in an ionic liquid solution. Both techniques require the production of radioisotopes combined with advanced spectroscopic instrumentation present at ISOLDE.

Original language	English
Article number	064003
Journal	Journal of Physics G: Nuclear and Particle Physics
Volume	44
Issue number	6
Number of pages	25
ISSN	0954-3899
DOIs	https://doi.org/10.1088/1361-6471/aa666b
Publication status	Published - 19 Apr 2017

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abstract = "Time differential perturbed angular correlation (TDPAC) of γ-rays spectroscopy has been applied in chemistry and biochemistry for decades. Herein we aim to present a comprehensive review of chemical and biochemical applications of TDPAC spectroscopy conducted at ISOLDE over the past 15 years, including elucidation of metal site structure and dynamics in proteins and model systems. β-NMR spectroscopy is well established in nuclear physics, solid state physics, and materials science, but only a limited number of applications in chemistry have appeared. Current endeavors at ISOLDE advancing applications of β-NMR towards chemistry and biochemistry are presented, including the first experiment on 31Mg2+ in an ionic liquid solution. Both techniques require the production of radioisotopes combined with advanced spectroscopic instrumentation present at ISOLDE.",

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AU - Jancso, Attila

AU - Correia, Joao G.

AU - Gottberg, Alexander

AU - Schell, Juliana

AU - Stachura, Monika

AU - Szunyogh, Daniel Mihaly

AU - Pallada, Stavroula

AU - Lupascu, Doru C.

AU - Kowalska, Magdalena

AU - Hemmingsen, Lars Bo Stegeager

PY - 2017/4/19

Y1 - 2017/4/19

N2 - Time differential perturbed angular correlation (TDPAC) of γ-rays spectroscopy has been applied in chemistry and biochemistry for decades. Herein we aim to present a comprehensive review of chemical and biochemical applications of TDPAC spectroscopy conducted at ISOLDE over the past 15 years, including elucidation of metal site structure and dynamics in proteins and model systems. β-NMR spectroscopy is well established in nuclear physics, solid state physics, and materials science, but only a limited number of applications in chemistry have appeared. Current endeavors at ISOLDE advancing applications of β-NMR towards chemistry and biochemistry are presented, including the first experiment on 31Mg2+ in an ionic liquid solution. Both techniques require the production of radioisotopes combined with advanced spectroscopic instrumentation present at ISOLDE.

AB - Time differential perturbed angular correlation (TDPAC) of γ-rays spectroscopy has been applied in chemistry and biochemistry for decades. Herein we aim to present a comprehensive review of chemical and biochemical applications of TDPAC spectroscopy conducted at ISOLDE over the past 15 years, including elucidation of metal site structure and dynamics in proteins and model systems. β-NMR spectroscopy is well established in nuclear physics, solid state physics, and materials science, but only a limited number of applications in chemistry have appeared. Current endeavors at ISOLDE advancing applications of β-NMR towards chemistry and biochemistry are presented, including the first experiment on 31Mg2+ in an ionic liquid solution. Both techniques require the production of radioisotopes combined with advanced spectroscopic instrumentation present at ISOLDE.

U2 - 10.1088/1361-6471/aa666b

DO - 10.1088/1361-6471/aa666b

M3 - Journal article

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JF - Journal of Physics G: Nuclear and Particle Physics

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TDPAC and β-NMR applications in chemistry and biochemistry

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