TDPAC and β-NMR applications in chemistry and biochemistry

Attila Jancso; Joao G. Correia; Alexander  Gottberg; Juliana  Schell; Monika  Stachura; Daniel Mihaly Szunyogh; Stavroula Pallada; Doru C. Lupascu; Magdalena Kowalska; Lars Bo Stegeager Hemmingsen

doi:10.1088/1361-6471/aa666b

TDPAC and β-NMR applications in chemistry and biochemistry

Attila Jancso, Joao G. Correia, Alexander Gottberg, Juliana Schell, Monika Stachura, Daniel Mihaly Szunyogh, Stavroula Pallada, Doru C. Lupascu, Magdalena Kowalska, Lars Bo Stegeager Hemmingsen

Kemisk Institut

11 Citationer (Scopus)

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Abstract

Time differential perturbed angular correlation (TDPAC) of γ-rays spectroscopy has been applied in chemistry and biochemistry for decades. Herein we aim to present a comprehensive review of chemical and biochemical applications of TDPAC spectroscopy conducted at ISOLDE over the past 15 years, including elucidation of metal site structure and dynamics in proteins and model systems. β-NMR spectroscopy is well established in nuclear physics, solid state physics, and materials science, but only a limited number of applications in chemistry have appeared. Current endeavors at ISOLDE advancing applications of β-NMR towards chemistry and biochemistry are presented, including the first experiment on ³¹Mg²⁺ in an ionic liquid solution. Both techniques require the production of radioisotopes combined with advanced spectroscopic instrumentation present at ISOLDE.

Originalsprog	Engelsk
Artikelnummer	064003
Tidsskrift	Journal of Physics G: Nuclear and Particle Physics
Vol/bind	44
Udgave nummer	6
Antal sider	25
ISSN	0954-3899
DOI	https://doi.org/10.1088/1361-6471/aa666b
Status	Udgivet - 19 apr. 2017

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10.1088/1361-6471/aa666bLicens: CC BY

TDPAC and β-NMR applications inForlagets udgivne version, 1,74 MBLicens: CC BY

Citationsformater

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AU - Jancso, Attila

AU - Correia, Joao G.

AU - Gottberg, Alexander

AU - Schell, Juliana

AU - Stachura, Monika

AU - Szunyogh, Daniel Mihaly

AU - Pallada, Stavroula

AU - Lupascu, Doru C.

AU - Kowalska, Magdalena

AU - Hemmingsen, Lars Bo Stegeager

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N2 - Time differential perturbed angular correlation (TDPAC) of γ-rays spectroscopy has been applied in chemistry and biochemistry for decades. Herein we aim to present a comprehensive review of chemical and biochemical applications of TDPAC spectroscopy conducted at ISOLDE over the past 15 years, including elucidation of metal site structure and dynamics in proteins and model systems. β-NMR spectroscopy is well established in nuclear physics, solid state physics, and materials science, but only a limited number of applications in chemistry have appeared. Current endeavors at ISOLDE advancing applications of β-NMR towards chemistry and biochemistry are presented, including the first experiment on 31Mg2+ in an ionic liquid solution. Both techniques require the production of radioisotopes combined with advanced spectroscopic instrumentation present at ISOLDE.

AB - Time differential perturbed angular correlation (TDPAC) of γ-rays spectroscopy has been applied in chemistry and biochemistry for decades. Herein we aim to present a comprehensive review of chemical and biochemical applications of TDPAC spectroscopy conducted at ISOLDE over the past 15 years, including elucidation of metal site structure and dynamics in proteins and model systems. β-NMR spectroscopy is well established in nuclear physics, solid state physics, and materials science, but only a limited number of applications in chemistry have appeared. Current endeavors at ISOLDE advancing applications of β-NMR towards chemistry and biochemistry are presented, including the first experiment on 31Mg2+ in an ionic liquid solution. Both techniques require the production of radioisotopes combined with advanced spectroscopic instrumentation present at ISOLDE.

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DO - 10.1088/1361-6471/aa666b

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ER -

TDPAC and β-NMR applications in chemistry and biochemistry

Abstract

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