Synthesis of tin-containing cyclodextrins as potential enzyme models

You Zhou; Lavinia G Marinescu-Pedersen; Christian Marcus Pedersen; Mikael Bols

doi:10.1002/ejoc.201200756

Synthesis of tin-containing cyclodextrins as potential enzyme models

You Zhou, Lavinia G Marinescu-Pedersen, Christian Marcus Pedersen, Mikael Bols

Department of Chemistry

9 Citations (Scopus)

Abstract

The synthesis and the characterization of two types of water-soluble β-cyclodextrin-supported organotin derivatives is described. These new tin-containing macromolecules were prepared through a free radical bishydrostannylation of the corresponding β-cyclodextrin propargylic ethers using Me ₂SnClH prepared in situ with AIBN as initiator. The tin moieties were attached both on the primary and on the secondary rim of β-cyclodextrin in excellent yield.

Original language	English
Journal	European Journal of Organic Chemistry
Volume	2012
Issue number	32
Pages (from-to)	6383-6389
Number of pages	7
ISSN	1434-193X
DOIs	https://doi.org/10.1002/ejoc.201200756
Publication status	Published - Nov 2012

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title = "Synthesis of tin-containing cyclodextrins as potential enzyme models",

abstract = "The synthesis and the characterization of two types of water-soluble β-cyclodextrin-supported organotin derivatives is described. These new tin-containing macromolecules were prepared through a free radical bishydrostannylation of the corresponding β-cyclodextrin propargylic ethers using Me 2SnClH prepared in situ with AIBN as initiator. The tin moieties were attached both on the primary and on the secondary rim of β-cyclodextrin in excellent yield.",

author = "You Zhou and Marinescu-Pedersen, {Lavinia G} and Pedersen, {Christian Marcus} and Mikael Bols",

year = "2012",

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doi = "10.1002/ejoc.201200756",

language = "English",

volume = "2012",

pages = "6383--6389",

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T1 - Synthesis of tin-containing cyclodextrins as potential enzyme models

AU - Zhou, You

AU - Marinescu-Pedersen, Lavinia G

AU - Pedersen, Christian Marcus

AU - Bols, Mikael

PY - 2012/11

Y1 - 2012/11

N2 - The synthesis and the characterization of two types of water-soluble β-cyclodextrin-supported organotin derivatives is described. These new tin-containing macromolecules were prepared through a free radical bishydrostannylation of the corresponding β-cyclodextrin propargylic ethers using Me 2SnClH prepared in situ with AIBN as initiator. The tin moieties were attached both on the primary and on the secondary rim of β-cyclodextrin in excellent yield.

AB - The synthesis and the characterization of two types of water-soluble β-cyclodextrin-supported organotin derivatives is described. These new tin-containing macromolecules were prepared through a free radical bishydrostannylation of the corresponding β-cyclodextrin propargylic ethers using Me 2SnClH prepared in situ with AIBN as initiator. The tin moieties were attached both on the primary and on the secondary rim of β-cyclodextrin in excellent yield.

U2 - 10.1002/ejoc.201200756

DO - 10.1002/ejoc.201200756

M3 - Journal article

SN - 1434-193X

VL - 2012

SP - 6383

EP - 6389

JO - European Journal of Organic Chemistry

JF - European Journal of Organic Chemistry

IS - 32

ER -

Synthesis of tin-containing cyclodextrins as potential enzyme models

Abstract

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