Synthesis of tin-containing cyclodextrins as potential enzyme models

TY - JOUR

T1 - Synthesis of tin-containing cyclodextrins as potential enzyme models

AU - Zhou, You

AU - Marinescu-Pedersen, Lavinia G

AU - Pedersen, Christian Marcus

AU - Bols, Mikael

PY - 2012/11

Y1 - 2012/11

N2 - The synthesis and the characterization of two types of water-soluble β-cyclodextrin-supported organotin derivatives is described. These new tin-containing macromolecules were prepared through a free radical bishydrostannylation of the corresponding β-cyclodextrin propargylic ethers using Me 2SnClH prepared in situ with AIBN as initiator. The tin moieties were attached both on the primary and on the secondary rim of β-cyclodextrin in excellent yield.

AB - The synthesis and the characterization of two types of water-soluble β-cyclodextrin-supported organotin derivatives is described. These new tin-containing macromolecules were prepared through a free radical bishydrostannylation of the corresponding β-cyclodextrin propargylic ethers using Me 2SnClH prepared in situ with AIBN as initiator. The tin moieties were attached both on the primary and on the secondary rim of β-cyclodextrin in excellent yield.

U2 - 10.1002/ejoc.201200756

DO - 10.1002/ejoc.201200756

M3 - Journal article

SN - 1434-193X

VL - 2012

SP - 6383

EP - 6389

JO - European Journal of Organic Chemistry

JF - European Journal of Organic Chemistry

IS - 32

ER -