Syntheses of 11-hydroxylated guaianolides

A. Lauridsen; Claus Cornett; T. Vulpius; P. Moldt; S. B. Christensen

Syntheses of 11-hydroxylated guaianolides

A. Lauridsen, Claus Cornett, T. Vulpius, P. Moldt, S. B. Christensen

9 Citations (Scopus)

Abstract

Two epimeric guaianolides, both prepared from alpha-santonin, were 11-hydroxylated using 2-phenylsulfonyl-3-phenyloxaziridine as a reagent. Extensive use of protecting groups enabled selective acylation of the 3- and 10-hydroxy groups.

Original language	Undefined/Unknown
Journal	Acta Chemica Scandinavica. Supplementum
Volume	50
Issue number	2
Pages (from-to)	150-157
Number of pages	8
ISSN	0065-1133
Publication status	Published - 1996

Cite this

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title = "Syntheses of 11-hydroxylated guaianolides",

abstract = "Two epimeric guaianolides, both prepared from alpha-santonin, were 11-hydroxylated using 2-phenylsulfonyl-3-phenyloxaziridine as a reagent. Extensive use of protecting groups enabled selective acylation of the 3- and 10-hydroxy groups.",

keywords = "sesquiterpene lactones thapsigargin chemistry",

author = "A. Lauridsen and Claus Cornett and T. Vulpius and P. Moldt and Christensen, {S. B.}",

year = "1996",

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journal = "Acta Chemica Scandinavica. Supplementum",

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TY - JOUR

T1 - Syntheses of 11-hydroxylated guaianolides

AU - Lauridsen, A.

AU - Cornett, Claus

AU - Vulpius, T.

AU - Moldt, P.

AU - Christensen, S. B.

PY - 1996

Y1 - 1996

N2 - Two epimeric guaianolides, both prepared from alpha-santonin, were 11-hydroxylated using 2-phenylsulfonyl-3-phenyloxaziridine as a reagent. Extensive use of protecting groups enabled selective acylation of the 3- and 10-hydroxy groups.

AB - Two epimeric guaianolides, both prepared from alpha-santonin, were 11-hydroxylated using 2-phenylsulfonyl-3-phenyloxaziridine as a reagent. Extensive use of protecting groups enabled selective acylation of the 3- and 10-hydroxy groups.

KW - sesquiterpene lactones thapsigargin chemistry

M3 - Tidsskriftartikel

SN - 0065-1133

VL - 50

SP - 150

EP - 157

JO - Acta Chemica Scandinavica. Supplementum

JF - Acta Chemica Scandinavica. Supplementum

IS - 2

ER -