Syntheses of 11-hydroxylated guaianolides

A. Lauridsen; Claus Cornett; T. Vulpius; P. Moldt; S. B. Christensen

Syntheses of 11-hydroxylated guaianolides

A. Lauridsen, Claus Cornett, T. Vulpius, P. Moldt, S. B. Christensen

9 Citationer (Scopus)

Abstract

Two epimeric guaianolides, both prepared from alpha-santonin, were 11-hydroxylated using 2-phenylsulfonyl-3-phenyloxaziridine as a reagent. Extensive use of protecting groups enabled selective acylation of the 3- and 10-hydroxy groups.

Originalsprog	Udefineret/Ukendt
Tidsskrift	Acta Chemica Scandinavica. Supplementum
Vol/bind	50
Udgave nummer	2
Sider (fra-til)	150-157
Antal sider	8
ISSN	0065-1133
Status	Udgivet - 1996

Emneord

sesquiterpene lactones thapsigargin chemistry

Citationsformater

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title = "Syntheses of 11-hydroxylated guaianolides",

abstract = "Two epimeric guaianolides, both prepared from alpha-santonin, were 11-hydroxylated using 2-phenylsulfonyl-3-phenyloxaziridine as a reagent. Extensive use of protecting groups enabled selective acylation of the 3- and 10-hydroxy groups.",

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TY - JOUR

T1 - Syntheses of 11-hydroxylated guaianolides

AU - Lauridsen, A.

AU - Cornett, Claus

AU - Vulpius, T.

AU - Moldt, P.

AU - Christensen, S. B.

PY - 1996

Y1 - 1996

N2 - Two epimeric guaianolides, both prepared from alpha-santonin, were 11-hydroxylated using 2-phenylsulfonyl-3-phenyloxaziridine as a reagent. Extensive use of protecting groups enabled selective acylation of the 3- and 10-hydroxy groups.

AB - Two epimeric guaianolides, both prepared from alpha-santonin, were 11-hydroxylated using 2-phenylsulfonyl-3-phenyloxaziridine as a reagent. Extensive use of protecting groups enabled selective acylation of the 3- and 10-hydroxy groups.

KW - sesquiterpene lactones thapsigargin chemistry

M3 - Tidsskriftartikel

SN - 0065-1133

VL - 50

SP - 150

EP - 157

JO - Acta Chemica Scandinavica. Supplementum

JF - Acta Chemica Scandinavica. Supplementum

IS - 2

ER -