Setting the anomeric effect against steric effects in simple acyclic acetals. Non-anomeric non-classical conformations. An n.m.r. and molecular mechanics investigation

J. Edgar Anderson; Katsuhiko Heki; Minoru Hirota; Flemming Steen Jørgensen

doi:10.1039/C39870000554

Setting the anomeric effect against steric effects in simple acyclic acetals. Non-anomeric non-classical conformations. An n.m.r. and molecular mechanics investigation

J. Edgar Anderson, Katsuhiko Heki, Minoru Hirota, Flemming Steen Jørgensen

18 Citations (Scopus)

Abstract

N.m.r. parameters for a series of simple aliphatic acetals indicate that the preferred conformation changes from the anomeric one found in formaldehyde dimethyl acetal (formal), to a new one whose structure is suggested by molecular mechanics calculations.

Original language	Undefined/Unknown
Journal	Chemical communications (Cambridge, England)
Volume	1987
Pages (from-to)	554-555
Number of pages	2
ISSN	1359-7345
DOIs	https://doi.org/10.1039/C39870000554
Publication status	Published - 1987

Access to Document

10.1039/C39870000554

http://dx.doi.org/10.1039/C39870000554

Cite this

Setting the anomeric effect against steric effects in simple acyclic acetals. Non-anomeric non-classical conformations. An n.m.r. and molecular mechanics investigation. / Anderson, J. Edgar; Heki, Katsuhiko; Hirota, Minoru et al.

In: Chemical communications (Cambridge, England), Vol. 1987, 1987, p. 554-555.

Research output: Contribution to journal › Journal article › Research › peer-review

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abstract = "N.m.r. parameters for a series of simple aliphatic acetals indicate that the preferred conformation changes from the anomeric one found in formaldehyde dimethyl acetal (formal), to a new one whose structure is suggested by molecular mechanics calculations.",

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