Setting the anomeric effect against steric effects in simple acyclic acetals. Non-anomeric non-classical conformations. An n.m.r. and molecular mechanics investigation

J. Edgar Anderson; Katsuhiko Heki; Minoru Hirota; Flemming Steen Jørgensen

doi:10.1039/C39870000554

Setting the anomeric effect against steric effects in simple acyclic acetals. Non-anomeric non-classical conformations. An n.m.r. and molecular mechanics investigation

J. Edgar Anderson, Katsuhiko Heki, Minoru Hirota, Flemming Steen Jørgensen

18 Citationer (Scopus)

Abstract

N.m.r. parameters for a series of simple aliphatic acetals indicate that the preferred conformation changes from the anomeric one found in formaldehyde dimethyl acetal (formal), to a new one whose structure is suggested by molecular mechanics calculations.

Originalsprog	Udefineret/Ukendt
Tidsskrift	Chemical communications (Cambridge, England)
Vol/bind	1987
Sider (fra-til)	554-555
Antal sider	2
ISSN	1359-7345
DOI	https://doi.org/10.1039/C39870000554
Status	Udgivet - 1987

Adgang til dokumentet

10.1039/C39870000554

http://dx.doi.org/10.1039/C39870000554

Citationsformater

Setting the anomeric effect against steric effects in simple acyclic acetals. Non-anomeric non-classical conformations. An n.m.r. and molecular mechanics investigation. / Anderson, J. Edgar; Heki, Katsuhiko; Hirota, Minoru et al.

I: Chemical communications (Cambridge, England), Bind 1987, 1987, s. 554-555.

Publikation: Bidrag til tidsskrift › Tidsskriftartikel › Forskning › peer review

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abstract = "N.m.r. parameters for a series of simple aliphatic acetals indicate that the preferred conformation changes from the anomeric one found in formaldehyde dimethyl acetal (formal), to a new one whose structure is suggested by molecular mechanics calculations.",

author = "Anderson, {J. Edgar} and Katsuhiko Heki and Minoru Hirota and J{\o}rgensen, {Flemming Steen}",

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AU - Heki, Katsuhiko

AU - Hirota, Minoru

AU - Jørgensen, Flemming Steen

PY - 1987

Y1 - 1987

N2 - N.m.r. parameters for a series of simple aliphatic acetals indicate that the preferred conformation changes from the anomeric one found in formaldehyde dimethyl acetal (formal), to a new one whose structure is suggested by molecular mechanics calculations.

AB - N.m.r. parameters for a series of simple aliphatic acetals indicate that the preferred conformation changes from the anomeric one found in formaldehyde dimethyl acetal (formal), to a new one whose structure is suggested by molecular mechanics calculations.

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DO - 10.1039/C39870000554

M3 - Tidsskriftartikel

SN - 1359-7345

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SP - 554

EP - 555

JO - Chemical Communications

JF - Chemical Communications

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