Self-assembly between dicarboxylate ions and binuclear europium complexes: moving to water-pH dependence and effects of buffers

Leila R. Hill; Thomas Just Sørensen; Octavia A. Blackburn; Asha Brown; Paul D. Beer; Stephen Faulkner

doi:10.1039/c2dt32009f

Self-assembly between dicarboxylate ions and binuclear europium complexes: moving to water-pH dependence and effects of buffers

Leila R. Hill, Thomas Just Sørensen, Octavia A. Blackburn, Asha Brown, Paul D. Beer, Stephen Faulkner

Department of Chemistry

12 Citations (Scopus)

Abstract

Binuclear lanthanide complexes consisting of two lanthanide binding domains in kinetically stable DO3A binding pockets linked by a 3-functionalized meta-xylyl bridge form stable 1:1 adducts with isophthalate and dinicotinate in water. The influence of buffer, pH and ligand structure on the binding of dinicotinate has been investigated.

Original language	English
Journal	Dalton Transactions
Volume	42
Issue number	1
Pages (from-to)	67-70
Number of pages	4
ISSN	1477-9226
DOIs	https://doi.org/10.1039/c2dt32009f
Publication status	Published - 7 Jan 2013

Access to Document

10.1039/c2dt32009f

Self-assembly between dicarboxylate ions and binuclear europium complexesFinal published version, 296 KB

Cite this

@article{df21956ee29c446ba6441ce4137c6d30,

title = "Self-assembly between dicarboxylate ions and binuclear europium complexes: moving to water-pH dependence and effects of buffers",

abstract = "Binuclear lanthanide complexes consisting of two lanthanide binding domains in kinetically stable DO3A binding pockets linked by a 3-functionalized meta-xylyl bridge form stable 1:1 adducts with isophthalate and dinicotinate in water. The influence of buffer, pH and ligand structure on the binding of dinicotinate has been investigated.",

author = "Hill, {Leila R.} and S{\o}rensen, {Thomas Just} and Blackburn, {Octavia A.} and Asha Brown and Beer, {Paul D.} and Stephen Faulkner",

year = "2013",

month = jan,

day = "7",

doi = "10.1039/c2dt32009f",

language = "English",

volume = "42",

pages = "67--70",

journal = "Acta chemica Scandinavica. Series A: Physical and inorganic chemistry",

issn = "1477-9226",

publisher = "Royal Society of Chemistry",

number = "1",

}

TY - JOUR

T1 - Self-assembly between dicarboxylate ions and binuclear europium complexes

T2 - moving to water-pH dependence and effects of buffers

AU - Hill, Leila R.

AU - Sørensen, Thomas Just

AU - Blackburn, Octavia A.

AU - Brown, Asha

AU - Beer, Paul D.

AU - Faulkner, Stephen

PY - 2013/1/7

Y1 - 2013/1/7

N2 - Binuclear lanthanide complexes consisting of two lanthanide binding domains in kinetically stable DO3A binding pockets linked by a 3-functionalized meta-xylyl bridge form stable 1:1 adducts with isophthalate and dinicotinate in water. The influence of buffer, pH and ligand structure on the binding of dinicotinate has been investigated.

AB - Binuclear lanthanide complexes consisting of two lanthanide binding domains in kinetically stable DO3A binding pockets linked by a 3-functionalized meta-xylyl bridge form stable 1:1 adducts with isophthalate and dinicotinate in water. The influence of buffer, pH and ligand structure on the binding of dinicotinate has been investigated.

U2 - 10.1039/c2dt32009f

DO - 10.1039/c2dt32009f

M3 - Journal article

C2 - 23108073

SN - 1477-9226

VL - 42

SP - 67

EP - 70

JO - Acta chemica Scandinavica. Series A: Physical and inorganic chemistry

JF - Acta chemica Scandinavica. Series A: Physical and inorganic chemistry

IS - 1

ER -

Self-assembly between dicarboxylate ions and binuclear europium complexes: moving to water-pH dependence and effects of buffers

Abstract

Access to Document

Fingerprint

Cite this