Self-assembly between dicarboxylate ions and binuclear europium complexes: moving to water-pH dependence and effects of buffers

Leila R. Hill; Thomas Just Sørensen; Octavia A. Blackburn; Asha Brown; Paul D. Beer; Stephen Faulkner

doi:10.1039/c2dt32009f

Self-assembly between dicarboxylate ions and binuclear europium complexes: moving to water-pH dependence and effects of buffers

Leila R. Hill, Thomas Just Sørensen, Octavia A. Blackburn, Asha Brown, Paul D. Beer, Stephen Faulkner

Kemisk Institut

12 Citationer (Scopus)

Abstract

Binuclear lanthanide complexes consisting of two lanthanide binding domains in kinetically stable DO3A binding pockets linked by a 3-functionalized meta-xylyl bridge form stable 1:1 adducts with isophthalate and dinicotinate in water. The influence of buffer, pH and ligand structure on the binding of dinicotinate has been investigated.

Originalsprog	Engelsk
Tidsskrift	Dalton Transactions
Vol/bind	42
Udgave nummer	1
Sider (fra-til)	67-70
Antal sider	4
ISSN	1477-9226
DOI	https://doi.org/10.1039/c2dt32009f
Status	Udgivet - 7 jan. 2013

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10.1039/c2dt32009f

Self-assembly between dicarboxylate ions and binuclear europium complexesForlagets udgivne version, 296 KB

Citationsformater

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abstract = "Binuclear lanthanide complexes consisting of two lanthanide binding domains in kinetically stable DO3A binding pockets linked by a 3-functionalized meta-xylyl bridge form stable 1:1 adducts with isophthalate and dinicotinate in water. The influence of buffer, pH and ligand structure on the binding of dinicotinate has been investigated.",

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T2 - moving to water-pH dependence and effects of buffers

AU - Hill, Leila R.

AU - Sørensen, Thomas Just

AU - Blackburn, Octavia A.

AU - Brown, Asha

AU - Beer, Paul D.

AU - Faulkner, Stephen

PY - 2013/1/7

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AB - Binuclear lanthanide complexes consisting of two lanthanide binding domains in kinetically stable DO3A binding pockets linked by a 3-functionalized meta-xylyl bridge form stable 1:1 adducts with isophthalate and dinicotinate in water. The influence of buffer, pH and ligand structure on the binding of dinicotinate has been investigated.

U2 - 10.1039/c2dt32009f

DO - 10.1039/c2dt32009f

M3 - Journal article

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SN - 1477-9226

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EP - 70

JO - Acta chemica Scandinavica. Series A: Physical and inorganic chemistry

JF - Acta chemica Scandinavica. Series A: Physical and inorganic chemistry

IS - 1

ER -

Self-assembly between dicarboxylate ions and binuclear europium complexes: moving to water-pH dependence and effects of buffers

Abstract

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