Rate constants for the reactions of OH radicals and Cl atoms with diethyl sulfide, Di‐n‐propyl sulfide, and Di‐n‐butyl sulfide

Ole J. Nielsen; Howard W. Sidebottom; Linda Nelson; Oliver Rattigan; Jack J. Treacy; Denis J. O'Farrell

doi:10.1002/kin.550220605

Rate constants for the reactions of OH radicals and Cl atoms with diethyl sulfide, Di‐n‐propyl sulfide, and Di‐n‐butyl sulfide

Ole J. Nielsen^*, Howard W. Sidebottom, Linda Nelson, Oliver Rattigan, Jack J. Treacy, Denis J. O'Farrell

^*Corresponding author for this work

Department of Chemistry

29 Citations (Scopus)

Abstract

Rate constants for the reactions of OH radicals and Cl atoms with diethyl sulfide (DES), di‐n‐propyl sulfide (DPS), and di‐n‐butyl sulfide (DBS) have been determined at 295 ± 3 K and a total pressure of 1 atm. Hydroxyl radical rate data was obtained using the absolute technique of pulse radiolysis combined with kinetic spectroscopy. The chlorine atom rate constants were measured using a conventional photolytic relative rate method. The rate constant for the reaction of Cl atoms with dimethyl sulfide (DMS) was also determined. The following rate constants were obtained: (Formula Presented.)

Original language	English
Journal	International Journal of Chemical Kinetics
Volume	22
Issue number	6
Pages (from-to)	603-612
Number of pages	10
ISSN	0538-8066
DOIs	https://doi.org/10.1002/kin.550220605
Publication status	Published - 1 Jan 1990

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Rate constants for the reactions of OH radicals and Cl atoms with diethyl sulfide, Di‐n‐propyl sulfide, and Di‐n‐butyl sulfide. / Nielsen, Ole J.; Sidebottom, Howard W.; Nelson, Linda et al.

In: International Journal of Chemical Kinetics, Vol. 22, No. 6, 01.01.1990, p. 603-612.

Research output: Contribution to journal › Journal article › Research › peer-review

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abstract = "Rate constants for the reactions of OH radicals and Cl atoms with diethyl sulfide (DES), di‐n‐propyl sulfide (DPS), and di‐n‐butyl sulfide (DBS) have been determined at 295 ± 3 K and a total pressure of 1 atm. Hydroxyl radical rate data was obtained using the absolute technique of pulse radiolysis combined with kinetic spectroscopy. The chlorine atom rate constants were measured using a conventional photolytic relative rate method. The rate constant for the reaction of Cl atoms with dimethyl sulfide (DMS) was also determined. The following rate constants were obtained: (Formula Presented.)",

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T1 - Rate constants for the reactions of OH radicals and Cl atoms with diethyl sulfide, Di‐n‐propyl sulfide, and Di‐n‐butyl sulfide

AU - Nielsen, Ole J.

AU - Sidebottom, Howard W.

AU - Nelson, Linda

AU - Rattigan, Oliver

AU - Treacy, Jack J.

AU - O'Farrell, Denis J.

PY - 1990/1/1

Y1 - 1990/1/1

N2 - Rate constants for the reactions of OH radicals and Cl atoms with diethyl sulfide (DES), di‐n‐propyl sulfide (DPS), and di‐n‐butyl sulfide (DBS) have been determined at 295 ± 3 K and a total pressure of 1 atm. Hydroxyl radical rate data was obtained using the absolute technique of pulse radiolysis combined with kinetic spectroscopy. The chlorine atom rate constants were measured using a conventional photolytic relative rate method. The rate constant for the reaction of Cl atoms with dimethyl sulfide (DMS) was also determined. The following rate constants were obtained: (Formula Presented.)

AB - Rate constants for the reactions of OH radicals and Cl atoms with diethyl sulfide (DES), di‐n‐propyl sulfide (DPS), and di‐n‐butyl sulfide (DBS) have been determined at 295 ± 3 K and a total pressure of 1 atm. Hydroxyl radical rate data was obtained using the absolute technique of pulse radiolysis combined with kinetic spectroscopy. The chlorine atom rate constants were measured using a conventional photolytic relative rate method. The rate constant for the reaction of Cl atoms with dimethyl sulfide (DMS) was also determined. The following rate constants were obtained: (Formula Presented.)

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Rate constants for the reactions of OH radicals and Cl atoms with diethyl sulfide, Di‐n‐propyl sulfide, and Di‐n‐butyl sulfide

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