Rate constants for the reactions of OH radicals and Cl atoms with diethyl sulfide, Di‐n‐propyl sulfide, and Di‐n‐butyl sulfide

TY - JOUR

T1 - Rate constants for the reactions of OH radicals and Cl atoms with diethyl sulfide, Di‐n‐propyl sulfide, and Di‐n‐butyl sulfide

AU - Nielsen, Ole J.

AU - Sidebottom, Howard W.

AU - Nelson, Linda

AU - Rattigan, Oliver

AU - Treacy, Jack J.

AU - O'Farrell, Denis J.

PY - 1990/1/1

Y1 - 1990/1/1

N2 - Rate constants for the reactions of OH radicals and Cl atoms with diethyl sulfide (DES), di‐n‐propyl sulfide (DPS), and di‐n‐butyl sulfide (DBS) have been determined at 295 ± 3 K and a total pressure of 1 atm. Hydroxyl radical rate data was obtained using the absolute technique of pulse radiolysis combined with kinetic spectroscopy. The chlorine atom rate constants were measured using a conventional photolytic relative rate method. The rate constant for the reaction of Cl atoms with dimethyl sulfide (DMS) was also determined. The following rate constants were obtained: (Formula Presented.)

AB - Rate constants for the reactions of OH radicals and Cl atoms with diethyl sulfide (DES), di‐n‐propyl sulfide (DPS), and di‐n‐butyl sulfide (DBS) have been determined at 295 ± 3 K and a total pressure of 1 atm. Hydroxyl radical rate data was obtained using the absolute technique of pulse radiolysis combined with kinetic spectroscopy. The chlorine atom rate constants were measured using a conventional photolytic relative rate method. The rate constant for the reaction of Cl atoms with dimethyl sulfide (DMS) was also determined. The following rate constants were obtained: (Formula Presented.)

UR - http://www.scopus.com/inward/record.url?scp=0025445270&partnerID=8YFLogxK

U2 - 10.1002/kin.550220605

DO - 10.1002/kin.550220605

M3 - Journal article

AN - SCOPUS:0025445270

SN - 0538-8066

VL - 22

SP - 603

EP - 612

JO - International Journal of Chemical Kinetics

JF - International Journal of Chemical Kinetics

IS - 6

ER -