Rate constants for the gas-phase reactions of OH radicals and Cl atoms with CH₃CH₂NO₂, CH₃CH₂CH₂NO₂, CH₃CH₂CH₂CH₂NO₂, and CH₃CH₂CH₂CH₂CH₂NO₂

TY - JOUR

T1 - Rate constants for the gas-phase reactions of OH radicals and Cl atoms with CH3CH2NO2, CH3CH2CH2NO2, CH3CH2CH2CH2NO2, and CH3CH2CH2CH2CH2NO2

AU - Nielsen, Ole J.

AU - Sidebottom, Howard W.

AU - O'Farrell, Denis J.

AU - Donlon, Michael

AU - Treacy, Jack

PY - 1989/4/7

Y1 - 1989/4/7

N2 - Rate constants for the reactions of OH radicals and Cl atoms with CH3CH2NO2, CH3CH2CH2NO2, CH3CH2CH2CH2NO2, and CH3CH2CH2CH2CH2NO2 have been determined at 295±3 K and a total pressure of approximately 1 atm. The OH rate data were obtained using both the absolute rate technique of pulse radiolysis combined with kinetic spectroscopy and a conventional photolytic relative rate method. The Cl rate constants were measured using only the relative rate method. The results are discussed in terms of reactivity trends.

AB - Rate constants for the reactions of OH radicals and Cl atoms with CH3CH2NO2, CH3CH2CH2NO2, CH3CH2CH2CH2NO2, and CH3CH2CH2CH2CH2NO2 have been determined at 295±3 K and a total pressure of approximately 1 atm. The OH rate data were obtained using both the absolute rate technique of pulse radiolysis combined with kinetic spectroscopy and a conventional photolytic relative rate method. The Cl rate constants were measured using only the relative rate method. The results are discussed in terms of reactivity trends.

UR - http://www.scopus.com/inward/record.url?scp=33646945923&partnerID=8YFLogxK

U2 - 10.1016/0009-2614(89)87099-X

DO - 10.1016/0009-2614(89)87099-X

M3 - Journal article

AN - SCOPUS:33646945923

SN - 0009-2614

VL - 156

SP - 312

EP - 318

JO - Chemical Physics Letters

JF - Chemical Physics Letters

IS - 4

ER -