Rate constants for the gas-phase reactions of OH radicals and Cl atoms with CH3CH2NO2, CH3CH2CH2NO2, CH3CH2CH2CH2NO2, and CH3CH2CH2CH2CH2NO2

Ole J. Nielsen; Howard W. Sidebottom; Denis J. O'Farrell; Michael Donlon; Jack Treacy

doi:10.1016/0009-2614(89)87099-X

Rate constants for the gas-phase reactions of OH radicals and Cl atoms with CH₃CH₂NO₂, CH₃CH₂CH₂NO₂, CH₃CH₂CH₂CH₂NO₂, and CH₃CH₂CH₂CH₂CH₂NO₂

Ole J. Nielsen^*, Howard W. Sidebottom, Denis J. O'Farrell, Michael Donlon, Jack Treacy

^*Corresponding author af dette arbejde

Kemisk Institut

18 Citationer (Scopus)

Abstract

Rate constants for the reactions of OH radicals and Cl atoms with CH₃CH₂NO₂, CH₃CH₂CH₂NO₂, CH₃CH₂CH₂CH₂NO₂, and CH₃CH₂CH₂CH₂CH₂NO₂ have been determined at 295±3 K and a total pressure of approximately 1 atm. The OH rate data were obtained using both the absolute rate technique of pulse radiolysis combined with kinetic spectroscopy and a conventional photolytic relative rate method. The Cl rate constants were measured using only the relative rate method. The results are discussed in terms of reactivity trends.

Originalsprog	Engelsk
Tidsskrift	Chemical Physics Letters
Vol/bind	156
Udgave nummer	4
Sider (fra-til)	312-318
Antal sider	7
ISSN	0009-2614
DOI	https://doi.org/10.1016/0009-2614(89)87099-X
Status	Udgivet - 7 apr. 1989

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title = "Rate constants for the gas-phase reactions of OH radicals and Cl atoms with CH3CH2NO2, CH3CH2CH2NO2, CH3CH2CH2CH2NO2, and CH3CH2CH2CH2CH2NO2",

abstract = "Rate constants for the reactions of OH radicals and Cl atoms with CH3CH2NO2, CH3CH2CH2NO2, CH3CH2CH2CH2NO2, and CH3CH2CH2CH2CH2NO2 have been determined at 295±3 K and a total pressure of approximately 1 atm. The OH rate data were obtained using both the absolute rate technique of pulse radiolysis combined with kinetic spectroscopy and a conventional photolytic relative rate method. The Cl rate constants were measured using only the relative rate method. The results are discussed in terms of reactivity trends.",

author = "Nielsen, {Ole J.} and Sidebottom, {Howard W.} and O'Farrell, {Denis J.} and Michael Donlon and Jack Treacy",

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doi = "10.1016/0009-2614(89)87099-X",

language = "English",

volume = "156",

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journal = "Chemical Physics Letters",

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T1 - Rate constants for the gas-phase reactions of OH radicals and Cl atoms with CH3CH2NO2, CH3CH2CH2NO2, CH3CH2CH2CH2NO2, and CH3CH2CH2CH2CH2NO2

AU - Nielsen, Ole J.

AU - Sidebottom, Howard W.

AU - O'Farrell, Denis J.

AU - Donlon, Michael

AU - Treacy, Jack

PY - 1989/4/7

Y1 - 1989/4/7

N2 - Rate constants for the reactions of OH radicals and Cl atoms with CH3CH2NO2, CH3CH2CH2NO2, CH3CH2CH2CH2NO2, and CH3CH2CH2CH2CH2NO2 have been determined at 295±3 K and a total pressure of approximately 1 atm. The OH rate data were obtained using both the absolute rate technique of pulse radiolysis combined with kinetic spectroscopy and a conventional photolytic relative rate method. The Cl rate constants were measured using only the relative rate method. The results are discussed in terms of reactivity trends.

AB - Rate constants for the reactions of OH radicals and Cl atoms with CH3CH2NO2, CH3CH2CH2NO2, CH3CH2CH2CH2NO2, and CH3CH2CH2CH2CH2NO2 have been determined at 295±3 K and a total pressure of approximately 1 atm. The OH rate data were obtained using both the absolute rate technique of pulse radiolysis combined with kinetic spectroscopy and a conventional photolytic relative rate method. The Cl rate constants were measured using only the relative rate method. The results are discussed in terms of reactivity trends.

UR - http://www.scopus.com/inward/record.url?scp=33646945923&partnerID=8YFLogxK

U2 - 10.1016/0009-2614(89)87099-X

DO - 10.1016/0009-2614(89)87099-X

M3 - Journal article

AN - SCOPUS:33646945923

SN - 0009-2614

VL - 156

SP - 312

EP - 318

JO - Chemical Physics Letters

JF - Chemical Physics Letters

IS - 4

ER -