Oxalyl chloride as a practical carbon monoxide source for carbonylation reactions

Steffen V F Hansen; Trond Ulven

doi:10.1021/acs.orglett.5b01252

Oxalyl chloride as a practical carbon monoxide source for carbonylation reactions

Steffen V F Hansen, Trond Ulven

49 Citations (Scopus)

Abstract

A method for generation of high-quality carbon monoxide by decomposition of oxalyl chloride in an aqueous hydroxide solution is described. The usefulness of the method is demonstrated in the synthesis of heterocycles and for hydroxy-, alkoxy-, amino-, and reductive carbonylation reactions, in several cases under milder conditions than previously reported.

Original language	English
Journal	Organic Letters
Volume	17
Issue number	11
Pages (from-to)	2832-2835
Number of pages	4
ISSN	1523-7060
DOIs	https://doi.org/10.1021/acs.orglett.5b01252
Publication status	Published - 5 Jun 2015

Access to Document

10.1021/acs.orglett.5b01252

Cite this

@article{59ba141b5bfb47ed9fabab80df35fb49,

title = "Oxalyl chloride as a practical carbon monoxide source for carbonylation reactions",

abstract = "A method for generation of high-quality carbon monoxide by decomposition of oxalyl chloride in an aqueous hydroxide solution is described. The usefulness of the method is demonstrated in the synthesis of heterocycles and for hydroxy-, alkoxy-, amino-, and reductive carbonylation reactions, in several cases under milder conditions than previously reported.",

author = "Hansen, {Steffen V F} and Trond Ulven",

year = "2015",

month = jun,

day = "5",

doi = "10.1021/acs.orglett.5b01252",

language = "English",

volume = "17",

pages = "2832--2835",

journal = "Organic Letters",

issn = "1523-7060",

publisher = "American Chemical Society",

number = "11",

}

TY - JOUR

T1 - Oxalyl chloride as a practical carbon monoxide source for carbonylation reactions

AU - Hansen, Steffen V F

AU - Ulven, Trond

PY - 2015/6/5

Y1 - 2015/6/5

N2 - A method for generation of high-quality carbon monoxide by decomposition of oxalyl chloride in an aqueous hydroxide solution is described. The usefulness of the method is demonstrated in the synthesis of heterocycles and for hydroxy-, alkoxy-, amino-, and reductive carbonylation reactions, in several cases under milder conditions than previously reported.

AB - A method for generation of high-quality carbon monoxide by decomposition of oxalyl chloride in an aqueous hydroxide solution is described. The usefulness of the method is demonstrated in the synthesis of heterocycles and for hydroxy-, alkoxy-, amino-, and reductive carbonylation reactions, in several cases under milder conditions than previously reported.

U2 - 10.1021/acs.orglett.5b01252

DO - 10.1021/acs.orglett.5b01252

M3 - Journal article

SN - 1523-7060

VL - 17

SP - 2832

EP - 2835

JO - Organic Letters

JF - Organic Letters

IS - 11

ER -

Oxalyl chloride as a practical carbon monoxide source for carbonylation reactions

Abstract

Access to Document

Fingerprint

Cite this