On the phosphite-mediated synthesis of dithiafulvenes and π-extended tetrathiafulvalenes

Simon Stubbe Schou; Christian Richard Parker; Kasper Lincke Rue; Karsten Stein Jennum; Johan Elias Vibenholt; Anders Kadziola; Mogens Brøndsted Nielsen

doi:10.1055/s-0032-1317921

On the phosphite-mediated synthesis of dithiafulvenes and π-extended tetrathiafulvalenes

Simon Stubbe Schou, Christian Richard Parker, Kasper Lincke Rue, Karsten Stein Jennum, Johan Elias Vibenholt, Anders Kadziola, Mogens Brøndsted Nielsen

Department of Chemistry

11 Citations (Scopus)

Abstract

By phosphite-mediated couplings between functionalized benzaldehydes and 1,3-dithiole-2-thiones we have obtained a variety of π-extended tetrathiafulvalenes (TTF). In particular, this method has provided a new stilbene-extended TTF with lateral alkyne functionalities, an H-type cruciform structure. This outcome is the result of a phosphite-mediated coupling between two aldehydes.

Original language	English
Journal	SYNLETT: Accounts and Rapid Communications in Chemical Synthesis
Volume	24
Issue number	2
Pages (from-to)	231-235
Number of pages	5
ISSN	0936-5214
DOIs	https://doi.org/10.1055/s-0032-1317921
Publication status	Published - 2013

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10.1055/s-0032-1317921

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abstract = "By phosphite-mediated couplings between functionalized benzaldehydes and 1,3-dithiole-2-thiones we have obtained a variety of π-extended tetrathiafulvalenes (TTF). In particular, this method has provided a new stilbene-extended TTF with lateral alkyne functionalities, an H-type cruciform structure. This outcome is the result of a phosphite-mediated coupling between two aldehydes.",

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AU - Schou, Simon Stubbe

AU - Parker, Christian Richard

AU - Rue, Kasper Lincke

AU - Jennum, Karsten Stein

AU - Vibenholt, Johan Elias

AU - Kadziola, Anders

AU - Nielsen, Mogens Brøndsted

PY - 2013

Y1 - 2013

N2 - By phosphite-mediated couplings between functionalized benzaldehydes and 1,3-dithiole-2-thiones we have obtained a variety of π-extended tetrathiafulvalenes (TTF). In particular, this method has provided a new stilbene-extended TTF with lateral alkyne functionalities, an H-type cruciform structure. This outcome is the result of a phosphite-mediated coupling between two aldehydes.

AB - By phosphite-mediated couplings between functionalized benzaldehydes and 1,3-dithiole-2-thiones we have obtained a variety of π-extended tetrathiafulvalenes (TTF). In particular, this method has provided a new stilbene-extended TTF with lateral alkyne functionalities, an H-type cruciform structure. This outcome is the result of a phosphite-mediated coupling between two aldehydes.

U2 - 10.1055/s-0032-1317921

DO - 10.1055/s-0032-1317921

M3 - Journal article

SN - 0936-5214

VL - 24

SP - 231

EP - 235

JO - Synlett

JF - Synlett

IS - 2

ER -

On the phosphite-mediated synthesis of dithiafulvenes and π-extended tetrathiafulvalenes

Abstract

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