On the phosphite-mediated synthesis of dithiafulvenes and π-extended tetrathiafulvalenes

Simon Stubbe Schou; Christian Richard Parker; Kasper Lincke Rue; Karsten Stein Jennum; Johan Elias Vibenholt; Anders Kadziola; Mogens Brøndsted Nielsen

doi:10.1055/s-0032-1317921

On the phosphite-mediated synthesis of dithiafulvenes and π-extended tetrathiafulvalenes

Simon Stubbe Schou, Christian Richard Parker, Kasper Lincke Rue, Karsten Stein Jennum, Johan Elias Vibenholt, Anders Kadziola, Mogens Brøndsted Nielsen

Kemisk Institut

11 Citationer (Scopus)

Abstract

By phosphite-mediated couplings between functionalized benzaldehydes and 1,3-dithiole-2-thiones we have obtained a variety of π-extended tetrathiafulvalenes (TTF). In particular, this method has provided a new stilbene-extended TTF with lateral alkyne functionalities, an H-type cruciform structure. This outcome is the result of a phosphite-mediated coupling between two aldehydes.

Originalsprog	Engelsk
Tidsskrift	SYNLETT: Accounts and Rapid Communications in Chemical Synthesis
Vol/bind	24
Udgave nummer	2
Sider (fra-til)	231-235
Antal sider	5
ISSN	0936-5214
DOI	https://doi.org/10.1055/s-0032-1317921
Status	Udgivet - 2013

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10.1055/s-0032-1317921

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abstract = "By phosphite-mediated couplings between functionalized benzaldehydes and 1,3-dithiole-2-thiones we have obtained a variety of π-extended tetrathiafulvalenes (TTF). In particular, this method has provided a new stilbene-extended TTF with lateral alkyne functionalities, an H-type cruciform structure. This outcome is the result of a phosphite-mediated coupling between two aldehydes.",

author = "Schou, {Simon Stubbe} and Parker, {Christian Richard} and Rue, {Kasper Lincke} and Jennum, {Karsten Stein} and Vibenholt, {Johan Elias} and Anders Kadziola and Nielsen, {Mogens Br{\o}ndsted}",

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T1 - On the phosphite-mediated synthesis of dithiafulvenes and π-extended tetrathiafulvalenes

AU - Schou, Simon Stubbe

AU - Parker, Christian Richard

AU - Rue, Kasper Lincke

AU - Jennum, Karsten Stein

AU - Vibenholt, Johan Elias

AU - Kadziola, Anders

AU - Nielsen, Mogens Brøndsted

PY - 2013

Y1 - 2013

N2 - By phosphite-mediated couplings between functionalized benzaldehydes and 1,3-dithiole-2-thiones we have obtained a variety of π-extended tetrathiafulvalenes (TTF). In particular, this method has provided a new stilbene-extended TTF with lateral alkyne functionalities, an H-type cruciform structure. This outcome is the result of a phosphite-mediated coupling between two aldehydes.

AB - By phosphite-mediated couplings between functionalized benzaldehydes and 1,3-dithiole-2-thiones we have obtained a variety of π-extended tetrathiafulvalenes (TTF). In particular, this method has provided a new stilbene-extended TTF with lateral alkyne functionalities, an H-type cruciform structure. This outcome is the result of a phosphite-mediated coupling between two aldehydes.

U2 - 10.1055/s-0032-1317921

DO - 10.1055/s-0032-1317921

M3 - Journal article

SN - 0936-5214

VL - 24

SP - 231

EP - 235

JO - SYNLETT: Accounts and Rapid Communications in Chemical Synthesis

JF - SYNLETT: Accounts and Rapid Communications in Chemical Synthesis

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ER -

On the phosphite-mediated synthesis of dithiafulvenes and π-extended tetrathiafulvalenes

Abstract

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