Influence of colloidal nano-silica on alkyd autoxidation

Miroslav Nikolic; Anand Ramesh Sanadi; David Löf; Søren Talbro Barsberg

doi:10.1007/s10853-017-0951-7

Influence of colloidal nano-silica on alkyd autoxidation

Miroslav Nikolic^*, Anand Ramesh Sanadi, David Löf, Søren Talbro Barsberg

^*Corresponding author for this work

Forest, Nature and Biomass

3 Citations (Scopus)

Abstract

Nanoparticles are often added to coatings in order to improve their mechanical properties. However, nanoparticles can also influence the cross-linking reaction of polymers and overall curing kinetics, and from this follows that properties of interest are further impacted. In research studies on alkyd-based coatings, only the physical drying stage during the first 24 h has been studied in this respect until now. In this study, it was shown with the use of Raman spectroscopy that colloidal nano-silica can change the rate of alkyd autoxidation and how this effect is reflected on the tensile properties of the coating. One of the consequences of the influence of nano-silica on curing kinetics is that, contrary to implicit assumptions of common testing methods, the real effect of nanoparticles on mechanical properties can emerge much later in the coating lifetime.

Original language	English
Journal	Journal of Materials Science
Volume	52
Issue number	12
Pages (from-to)	7158-7165
Number of pages	8
ISSN	0022-2461
DOIs	https://doi.org/10.1007/s10853-017-0951-7
Publication status	Published - 2017

Access to Document

10.1007/s10853-017-0951-7

Cite this

@article{39c433e5293248a89afab6716c3a037c,

title = "Influence of colloidal nano-silica on alkyd autoxidation",

abstract = "Nanoparticles are often added to coatings in order to improve their mechanical properties. However, nanoparticles can also influence the cross-linking reaction of polymers and overall curing kinetics, and from this follows that properties of interest are further impacted. In research studies on alkyd-based coatings, only the physical drying stage during the first 24 h has been studied in this respect until now. In this study, it was shown with the use of Raman spectroscopy that colloidal nano-silica can change the rate of alkyd autoxidation and how this effect is reflected on the tensile properties of the coating. One of the consequences of the influence of nano-silica on curing kinetics is that, contrary to implicit assumptions of common testing methods, the real effect of nanoparticles on mechanical properties can emerge much later in the coating lifetime.",

author = "Miroslav Nikolic and Sanadi, {Anand Ramesh} and David L{\"o}f and Barsberg, {S{\o}ren Talbro}",

year = "2017",

doi = "10.1007/s10853-017-0951-7",

language = "English",

volume = "52",

pages = "7158--7165",

journal = "Journal of Materials Science",

issn = "0022-2461",

publisher = "Springer",

number = "12",

}

TY - JOUR

T1 - Influence of colloidal nano-silica on alkyd autoxidation

AU - Nikolic, Miroslav

AU - Sanadi, Anand Ramesh

AU - Löf, David

AU - Barsberg, Søren Talbro

PY - 2017

Y1 - 2017

N2 - Nanoparticles are often added to coatings in order to improve their mechanical properties. However, nanoparticles can also influence the cross-linking reaction of polymers and overall curing kinetics, and from this follows that properties of interest are further impacted. In research studies on alkyd-based coatings, only the physical drying stage during the first 24 h has been studied in this respect until now. In this study, it was shown with the use of Raman spectroscopy that colloidal nano-silica can change the rate of alkyd autoxidation and how this effect is reflected on the tensile properties of the coating. One of the consequences of the influence of nano-silica on curing kinetics is that, contrary to implicit assumptions of common testing methods, the real effect of nanoparticles on mechanical properties can emerge much later in the coating lifetime.

AB - Nanoparticles are often added to coatings in order to improve their mechanical properties. However, nanoparticles can also influence the cross-linking reaction of polymers and overall curing kinetics, and from this follows that properties of interest are further impacted. In research studies on alkyd-based coatings, only the physical drying stage during the first 24 h has been studied in this respect until now. In this study, it was shown with the use of Raman spectroscopy that colloidal nano-silica can change the rate of alkyd autoxidation and how this effect is reflected on the tensile properties of the coating. One of the consequences of the influence of nano-silica on curing kinetics is that, contrary to implicit assumptions of common testing methods, the real effect of nanoparticles on mechanical properties can emerge much later in the coating lifetime.

U2 - 10.1007/s10853-017-0951-7

DO - 10.1007/s10853-017-0951-7

M3 - Journal article

AN - SCOPUS:85014095613

SN - 0022-2461

VL - 52

SP - 7158

EP - 7165

JO - Journal of Materials Science

JF - Journal of Materials Science

IS - 12

ER -

Influence of colloidal nano-silica on alkyd autoxidation

Abstract

Access to Document

Fingerprint

Cite this