Identification of the water amidogen radical complex

Courtney P Ennis; Joseph R Lane; Henrik G Kjaergaard; Allan J McKinley

doi:10.1021/ja808109m

Identification of the water amidogen radical complex

Courtney P Ennis, Joseph R Lane, Henrik G Kjaergaard, Allan J McKinley

Department of Chemistry

18 Citations (Scopus)

Abstract

The water amidogen radical complex (H(2)O-NH(2)) is a reactive intermediate in the atmospheric oxidation of ammonia by a hydroxyl radical. In the present study, we identify for the first time the H(2)O-NH(2) complex using matrix isolation infrared spectroscopy. We corroborate our experimental findings with high level coupled cluster ab initio calculations.

Original language	English
Journal	Journal of the American Chemical Society
Volume	131
Pages (from-to)	1358-9
ISSN	0002-7863
DOIs	https://doi.org/10.1021/ja808109m
Publication status	Published - 4 Feb 2009

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title = "Identification of the water amidogen radical complex",

abstract = "The water amidogen radical complex (H(2)O-NH(2)) is a reactive intermediate in the atmospheric oxidation of ammonia by a hydroxyl radical. In the present study, we identify for the first time the H(2)O-NH(2) complex using matrix isolation infrared spectroscopy. We corroborate our experimental findings with high level coupled cluster ab initio calculations.",

author = "Ennis, {Courtney P} and Lane, {Joseph R} and Kjaergaard, {Henrik G} and McKinley, {Allan J}",

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AU - Ennis, Courtney P

AU - Lane, Joseph R

AU - Kjaergaard, Henrik G

AU - McKinley, Allan J

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Y1 - 2009/2/4

N2 - The water amidogen radical complex (H(2)O-NH(2)) is a reactive intermediate in the atmospheric oxidation of ammonia by a hydroxyl radical. In the present study, we identify for the first time the H(2)O-NH(2) complex using matrix isolation infrared spectroscopy. We corroborate our experimental findings with high level coupled cluster ab initio calculations.

AB - The water amidogen radical complex (H(2)O-NH(2)) is a reactive intermediate in the atmospheric oxidation of ammonia by a hydroxyl radical. In the present study, we identify for the first time the H(2)O-NH(2) complex using matrix isolation infrared spectroscopy. We corroborate our experimental findings with high level coupled cluster ab initio calculations.

U2 - 10.1021/ja808109m

DO - 10.1021/ja808109m

M3 - Journal article

C2 - 19173661

SN - 0002-7863

VL - 131

SP - 1358

EP - 1359

JO - Journal of the American Chemical Society

JF - Journal of the American Chemical Society

ER -

Identification of the water amidogen radical complex

Abstract

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