Identification of the water amidogen radical complex

Courtney P Ennis; Joseph R Lane; Henrik G Kjaergaard; Allan J McKinley

doi:10.1021/ja808109m

Identification of the water amidogen radical complex

Courtney P Ennis, Joseph R Lane, Henrik G Kjaergaard, Allan J McKinley

Kemisk Institut

18 Citationer (Scopus)

Abstract

The water amidogen radical complex (H(2)O-NH(2)) is a reactive intermediate in the atmospheric oxidation of ammonia by a hydroxyl radical. In the present study, we identify for the first time the H(2)O-NH(2) complex using matrix isolation infrared spectroscopy. We corroborate our experimental findings with high level coupled cluster ab initio calculations.

Originalsprog	Engelsk
Tidsskrift	Journal of the American Chemical Society
Vol/bind	131
Sider (fra-til)	1358-9
ISSN	0002-7863
DOI	https://doi.org/10.1021/ja808109m
Status	Udgivet - 4 feb. 2009

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10.1021/ja808109m

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abstract = "The water amidogen radical complex (H(2)O-NH(2)) is a reactive intermediate in the atmospheric oxidation of ammonia by a hydroxyl radical. In the present study, we identify for the first time the H(2)O-NH(2) complex using matrix isolation infrared spectroscopy. We corroborate our experimental findings with high level coupled cluster ab initio calculations.",

author = "Ennis, {Courtney P} and Lane, {Joseph R} and Kjaergaard, {Henrik G} and McKinley, {Allan J}",

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T1 - Identification of the water amidogen radical complex

AU - Ennis, Courtney P

AU - Lane, Joseph R

AU - Kjaergaard, Henrik G

AU - McKinley, Allan J

PY - 2009/2/4

Y1 - 2009/2/4

N2 - The water amidogen radical complex (H(2)O-NH(2)) is a reactive intermediate in the atmospheric oxidation of ammonia by a hydroxyl radical. In the present study, we identify for the first time the H(2)O-NH(2) complex using matrix isolation infrared spectroscopy. We corroborate our experimental findings with high level coupled cluster ab initio calculations.

AB - The water amidogen radical complex (H(2)O-NH(2)) is a reactive intermediate in the atmospheric oxidation of ammonia by a hydroxyl radical. In the present study, we identify for the first time the H(2)O-NH(2) complex using matrix isolation infrared spectroscopy. We corroborate our experimental findings with high level coupled cluster ab initio calculations.

U2 - 10.1021/ja808109m

DO - 10.1021/ja808109m

M3 - Journal article

C2 - 19173661

SN - 0002-7863

VL - 131

SP - 1358

EP - 1359

JO - Journal of the American Chemical Society

JF - Journal of the American Chemical Society

ER -

Identification of the water amidogen radical complex

Abstract

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