Abstract
A new simple protocol, using TMSNTf2 or Tf2NH as the catalyst, for the activation of trichloroacetimidate donors is described. This O-glycosylation proceeds with stereospecific inversion of the donor configuration. The scope of the protocol has been investigated using common glycosyl donors reacting with simple alcohols as well as sugar acceptors
| Original language | English |
|---|---|
| Journal | Chemical Communications |
| Volume | 53 |
| Issue number | 12 |
| Pages (from-to) | 2040-2043 |
| Number of pages | 4 |
| ISSN | 1359-7345 |
| DOIs | |
| Publication status | Published - 2017 |