Calix[4]arene supported clusters: a dimer of [Mn(III)Mn(II)] dimers

Stephanie M Taylor; Ruaraidh D McIntosh; Christine M Beavers; Simon J Teat; Stergios Piligkos; Scott J Dalgarno; Euan K Brechin

doi:10.1039/c0cc04466k

Calix[4]arene supported clusters: a dimer of [Mn(III)Mn(II)] dimers

Stephanie M Taylor, Ruaraidh D McIntosh, Christine M Beavers, Simon J Teat, Stergios Piligkos, Scott J Dalgarno, Euan K Brechin

Department of Chemistry

24 Citations (Scopus)

Abstract

Phosphinate ligands allow for the transformation of a calix[4]arene supported [Mn(III)(2)Mn(II)(2)] tetramer cluster motif into an unusual [Mn(III)Mn(II)](2) dimer of dimers; the clusters self-assemble in the crystal to form bi-layer arrays reminiscent of the typical packing of calixarene solvates.

Original language	English
Journal	Chemical Communications
Volume	47
Issue number	5
Pages (from-to)	1440-2
Number of pages	3
ISSN	1359-7345
DOIs	https://doi.org/10.1039/c0cc04466k
Publication status	Published - 7 Feb 2011

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title = "Calix[4]arene supported clusters: a dimer of [Mn(III)Mn(II)] dimers",

abstract = "Phosphinate ligands allow for the transformation of a calix[4]arene supported [Mn(III)(2)Mn(II)(2)] tetramer cluster motif into an unusual [Mn(III)Mn(II)](2) dimer of dimers; the clusters self-assemble in the crystal to form bi-layer arrays reminiscent of the typical packing of calixarene solvates.",

author = "Taylor, {Stephanie M} and McIntosh, {Ruaraidh D} and Beavers, {Christine M} and Teat, {Simon J} and Stergios Piligkos and Dalgarno, {Scott J} and Brechin, {Euan K}",

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language = "English",

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T1 - Calix[4]arene supported clusters: a dimer of [Mn(III)Mn(II)] dimers

AU - Taylor, Stephanie M

AU - McIntosh, Ruaraidh D

AU - Beavers, Christine M

AU - Teat, Simon J

AU - Piligkos, Stergios

AU - Dalgarno, Scott J

AU - Brechin, Euan K

PY - 2011/2/7

Y1 - 2011/2/7

N2 - Phosphinate ligands allow for the transformation of a calix[4]arene supported [Mn(III)(2)Mn(II)(2)] tetramer cluster motif into an unusual [Mn(III)Mn(II)](2) dimer of dimers; the clusters self-assemble in the crystal to form bi-layer arrays reminiscent of the typical packing of calixarene solvates.

AB - Phosphinate ligands allow for the transformation of a calix[4]arene supported [Mn(III)(2)Mn(II)(2)] tetramer cluster motif into an unusual [Mn(III)Mn(II)](2) dimer of dimers; the clusters self-assemble in the crystal to form bi-layer arrays reminiscent of the typical packing of calixarene solvates.

U2 - 10.1039/c0cc04466k

DO - 10.1039/c0cc04466k

M3 - Journal article

C2 - 21161081

SN - 1359-7345

VL - 47

SP - 1440

EP - 1442

JO - Chemical Communications

JF - Chemical Communications

IS - 5

ER -

Calix[4]arene supported clusters: a dimer of [Mn(III)Mn(II)] dimers

Abstract

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