Calix[4]arene supported clusters: a dimer of [Mn(III)Mn(II)] dimers

Stephanie M Taylor, Ruaraidh D McIntosh, Christine M Beavers, Simon J Teat, Stergios Piligkos, Scott J Dalgarno, Euan K Brechin

24 Citationer (Scopus)

Abstract

Phosphinate ligands allow for the transformation of a calix[4]arene supported [Mn(III)(2)Mn(II)(2)] tetramer cluster motif into an unusual [Mn(III)Mn(II)](2) dimer of dimers; the clusters self-assemble in the crystal to form bi-layer arrays reminiscent of the typical packing of calixarene solvates.
OriginalsprogEngelsk
TidsskriftChemical Communications
Vol/bind47
Udgave nummer5
Sider (fra-til)1440-2
Antal sider3
ISSN1359-7345
DOI
StatusUdgivet - 7 feb. 2011

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