Atmospheric Chemistry of Methoxyflurane (CH3OCF2CHCl2): Kinetics of the gas-phase reactions with OH radicals, Cl atoms and O3

Sofie A. Hass; Simone Thirstrup Andersen; Mads P. Sulbaek Andersen; Ole J. Nielsen

doi:10.1016/j.cplett.2019.02.041

Atmospheric Chemistry of Methoxyflurane (CH₃OCF₂CHCl₂): Kinetics of the gas-phase reactions with OH radicals, Cl atoms and O₃

Sofie A. Hass, Simone Thirstrup Andersen, Mads P. Sulbaek Andersen^*, Ole J. Nielsen

^*Corresponding author for this work

Department of Chemistry

4 Citations (Scopus)

Abstract

Smog chamber techniques were used to determine k(CH ₃ OCF ₂ CHCl ₂ + Cl) = (5.04 ± 0.75) × 10 ⁻¹³ , k(CH ₃ OCF ₂ CHCl ₂ + OH) = (2.18 ± 0.38) × 10 ⁻¹³ , and k(CH ₃ OCF ₂ CHCl ₂ + O ₃ ) < 1.5 × 10 ⁻²² cm ³ molecule ⁻¹ s ⁻¹ in 700 Torr of N ₂ /air diluent at 296–300 K. The IR spectrum for CH ₃ OCF ₂ CHCl ₂ is reported. CH ₃ OCF ₂ CHCl ₂ is a short-lived compound with an estimated atmospheric lifetime of ∼54 days. The ozone depletion potential for CH ₃ OCF ₂ CHCl ₂ was estimated to be on the order of 0.001 and a 100-year global warming potential of 4 was determined using a lifetime-corrected radiative efficiency estimation. Results are discussed with respect to the atmospheric chemistry of halogenated anesthetic gases.

Original language	English
Journal	Chemical Physics Letters
Volume	722
Pages (from-to)	119-123
Number of pages	5
ISSN	0009-2614
DOIs	https://doi.org/10.1016/j.cplett.2019.02.041
Publication status	Published - 2019

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Cite this

@article{d3c22ca29ca74a0382371eb9445625ae,

title = "Atmospheric Chemistry of Methoxyflurane (CH3OCF2CHCl2): Kinetics of the gas-phase reactions with OH radicals, Cl atoms and O3",

abstract = " Smog chamber techniques were used to determine k(CH 3 OCF 2 CHCl 2 + Cl) = (5.04 ± 0.75) × 10 −13 , k(CH 3 OCF 2 CHCl 2 + OH) = (2.18 ± 0.38) × 10 −13 , and k(CH 3 OCF 2 CHCl 2 + O 3 ) < 1.5 × 10 −22 cm 3 molecule −1 s −1 in 700 Torr of N 2 /air diluent at 296–300 K. The IR spectrum for CH 3 OCF 2 CHCl 2 is reported. CH 3 OCF 2 CHCl 2 is a short-lived compound with an estimated atmospheric lifetime of ∼54 days. The ozone depletion potential for CH 3 OCF 2 CHCl 2 was estimated to be on the order of 0.001 and a 100-year global warming potential of 4 was determined using a lifetime-corrected radiative efficiency estimation. Results are discussed with respect to the atmospheric chemistry of halogenated anesthetic gases. ",

author = "Hass, {Sofie A.} and Andersen, {Simone Thirstrup} and {Sulbaek Andersen}, {Mads P.} and Nielsen, {Ole J.}",

year = "2019",

doi = "10.1016/j.cplett.2019.02.041",

language = "English",

volume = "722",

pages = "119--123",

journal = "Chemical Physics Letters",

issn = "0009-2614",

publisher = "Elsevier",

}

TY - JOUR

T1 - Atmospheric Chemistry of Methoxyflurane (CH3OCF2CHCl2)

T2 - Kinetics of the gas-phase reactions with OH radicals, Cl atoms and O3

AU - Hass, Sofie A.

AU - Andersen, Simone Thirstrup

AU - Sulbaek Andersen, Mads P.

AU - Nielsen, Ole J.

PY - 2019

Y1 - 2019

N2 - Smog chamber techniques were used to determine k(CH 3 OCF 2 CHCl 2 + Cl) = (5.04 ± 0.75) × 10 −13 , k(CH 3 OCF 2 CHCl 2 + OH) = (2.18 ± 0.38) × 10 −13 , and k(CH 3 OCF 2 CHCl 2 + O 3 ) < 1.5 × 10 −22 cm 3 molecule −1 s −1 in 700 Torr of N 2 /air diluent at 296–300 K. The IR spectrum for CH 3 OCF 2 CHCl 2 is reported. CH 3 OCF 2 CHCl 2 is a short-lived compound with an estimated atmospheric lifetime of ∼54 days. The ozone depletion potential for CH 3 OCF 2 CHCl 2 was estimated to be on the order of 0.001 and a 100-year global warming potential of 4 was determined using a lifetime-corrected radiative efficiency estimation. Results are discussed with respect to the atmospheric chemistry of halogenated anesthetic gases.

AB - Smog chamber techniques were used to determine k(CH 3 OCF 2 CHCl 2 + Cl) = (5.04 ± 0.75) × 10 −13 , k(CH 3 OCF 2 CHCl 2 + OH) = (2.18 ± 0.38) × 10 −13 , and k(CH 3 OCF 2 CHCl 2 + O 3 ) < 1.5 × 10 −22 cm 3 molecule −1 s −1 in 700 Torr of N 2 /air diluent at 296–300 K. The IR spectrum for CH 3 OCF 2 CHCl 2 is reported. CH 3 OCF 2 CHCl 2 is a short-lived compound with an estimated atmospheric lifetime of ∼54 days. The ozone depletion potential for CH 3 OCF 2 CHCl 2 was estimated to be on the order of 0.001 and a 100-year global warming potential of 4 was determined using a lifetime-corrected radiative efficiency estimation. Results are discussed with respect to the atmospheric chemistry of halogenated anesthetic gases.

U2 - 10.1016/j.cplett.2019.02.041

DO - 10.1016/j.cplett.2019.02.041

M3 - Journal article

AN - SCOPUS:85063046348

SN - 0009-2614

VL - 722

SP - 119

EP - 123

JO - Chemical Physics Letters

JF - Chemical Physics Letters

ER -