TY - JOUR
T1 - Absolute rate constants for the reaction of NO3 radicals with a series of dienes at 295 K
AU - Ellermann, Thomas
AU - Nielsen, Ole John
AU - Skov, Henrik
PY - 1992/12/4
Y1 - 1992/12/4
N2 - The rate constants for the reaction of NO3 radicals with a series of 7 dienes, 1,3-butadiene, isoprene, 2,3-dimethyl-1,3-butadiene, trans-1,3-pentadiene, cis-1,3-pentadiene, trans,trans-2,4-hexadiene, and 1,3-cyclohexadiene, were measured at 295 K and at a total pressure of 1 atm. The rate constant were obtained using the absolute technique of pulse radiolysis combined with kinetic UV-VIS spectroscopy. The results are discussed in terms of reactivity trends and previous literature data.
AB - The rate constants for the reaction of NO3 radicals with a series of 7 dienes, 1,3-butadiene, isoprene, 2,3-dimethyl-1,3-butadiene, trans-1,3-pentadiene, cis-1,3-pentadiene, trans,trans-2,4-hexadiene, and 1,3-cyclohexadiene, were measured at 295 K and at a total pressure of 1 atm. The rate constant were obtained using the absolute technique of pulse radiolysis combined with kinetic UV-VIS spectroscopy. The results are discussed in terms of reactivity trends and previous literature data.
UR - http://www.scopus.com/inward/record.url?scp=0001114142&partnerID=8YFLogxK
U2 - 10.1016/0009-2614(92)80002-S
DO - 10.1016/0009-2614(92)80002-S
M3 - Journal article
AN - SCOPUS:0001114142
SN - 0009-2614
VL - 200
SP - 224
EP - 229
JO - Chemical Physics Letters
JF - Chemical Physics Letters
IS - 3
ER -