Absolute rate constants for the reaction of NO3 radicals with a series of dienes at 295 K

TY - JOUR

T1 - Absolute rate constants for the reaction of NO3 radicals with a series of dienes at 295 K

AU - Ellermann, Thomas

AU - Nielsen, Ole John

AU - Skov, Henrik

PY - 1992/12/4

Y1 - 1992/12/4

N2 - The rate constants for the reaction of NO3 radicals with a series of 7 dienes, 1,3-butadiene, isoprene, 2,3-dimethyl-1,3-butadiene, trans-1,3-pentadiene, cis-1,3-pentadiene, trans,trans-2,4-hexadiene, and 1,3-cyclohexadiene, were measured at 295 K and at a total pressure of 1 atm. The rate constant were obtained using the absolute technique of pulse radiolysis combined with kinetic UV-VIS spectroscopy. The results are discussed in terms of reactivity trends and previous literature data.

AB - The rate constants for the reaction of NO3 radicals with a series of 7 dienes, 1,3-butadiene, isoprene, 2,3-dimethyl-1,3-butadiene, trans-1,3-pentadiene, cis-1,3-pentadiene, trans,trans-2,4-hexadiene, and 1,3-cyclohexadiene, were measured at 295 K and at a total pressure of 1 atm. The rate constant were obtained using the absolute technique of pulse radiolysis combined with kinetic UV-VIS spectroscopy. The results are discussed in terms of reactivity trends and previous literature data.

UR - http://www.scopus.com/inward/record.url?scp=0001114142&partnerID=8YFLogxK

U2 - 10.1016/0009-2614(92)80002-S

DO - 10.1016/0009-2614(92)80002-S

M3 - Journal article

AN - SCOPUS:0001114142

SN - 0009-2614

VL - 200

SP - 224

EP - 229

JO - Chemical Physics Letters

JF - Chemical Physics Letters

IS - 3

ER -