Synthesis and thermotropic phase behavior of four glycoglycerolipids

Wouter Frederik Johan Hogendorf; Vivien Jagalski; Thomas Günther-Pomorski; Mikael Bols; Marite Cardenas Gomez; Christian Marcus Pedersen

doi:10.3390/molecules181113546

Synthesis and thermotropic phase behavior of four glycoglycerolipids

Wouter Frederik Johan Hogendorf, Vivien Jagalski, Thomas Günther-Pomorski, Mikael Bols, Marite Cardenas Gomez, Christian Marcus Pedersen

5 Citationer (Scopus)

Abstract

Four glycoglycerolipids with different head groups have been synthesized and their physicochemical properties studied. The lengths of the head groups from a mono-saccharide to a trisaccharide, in addition to the anomeric stereochemistry for the smaller glycoglycerolipids, have been modified. The synthesis has been optimized to avoid glycerol epimerization and to allow up-scaling. The physicochemical properties of the glycoglycerolipids were studied and a strong de-mixing of the gel-phase, depending on the head-group, was observed.

Originalsprog	Engelsk
Tidsskrift	Molecules
Vol/bind	18
Udgave nummer	11
Sider (fra-til)	13546-13573
Antal sider	28
ISSN	1420-3049
DOI	https://doi.org/10.3390/molecules181113546
Status	Udgivet - nov. 2013

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10.3390/molecules181113546

Citationsformater

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title = "Synthesis and thermotropic phase behavior of four glycoglycerolipids",

abstract = "Four glycoglycerolipids with different head groups have been synthesized and their physicochemical properties studied. The lengths of the head groups from a mono-saccharide to a trisaccharide, in addition to the anomeric stereochemistry for the smaller glycoglycerolipids, have been modified. The synthesis has been optimized to avoid glycerol epimerization and to allow up-scaling. The physicochemical properties of the glycoglycerolipids were studied and a strong de-mixing of the gel-phase, depending on the head-group, was observed.",

author = "Hogendorf, {Wouter Frederik Johan} and Vivien Jagalski and Thomas G{\"u}nther-Pomorski and Mikael Bols and {Cardenas Gomez}, Marite and Pedersen, {Christian Marcus}",

year = "2013",

month = nov,

doi = "10.3390/molecules181113546",

language = "English",

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T1 - Synthesis and thermotropic phase behavior of four glycoglycerolipids

AU - Hogendorf, Wouter Frederik Johan

AU - Jagalski, Vivien

AU - Günther-Pomorski, Thomas

AU - Bols, Mikael

AU - Cardenas Gomez, Marite

AU - Pedersen, Christian Marcus

PY - 2013/11

Y1 - 2013/11

N2 - Four glycoglycerolipids with different head groups have been synthesized and their physicochemical properties studied. The lengths of the head groups from a mono-saccharide to a trisaccharide, in addition to the anomeric stereochemistry for the smaller glycoglycerolipids, have been modified. The synthesis has been optimized to avoid glycerol epimerization and to allow up-scaling. The physicochemical properties of the glycoglycerolipids were studied and a strong de-mixing of the gel-phase, depending on the head-group, was observed.

AB - Four glycoglycerolipids with different head groups have been synthesized and their physicochemical properties studied. The lengths of the head groups from a mono-saccharide to a trisaccharide, in addition to the anomeric stereochemistry for the smaller glycoglycerolipids, have been modified. The synthesis has been optimized to avoid glycerol epimerization and to allow up-scaling. The physicochemical properties of the glycoglycerolipids were studied and a strong de-mixing of the gel-phase, depending on the head-group, was observed.

U2 - 10.3390/molecules181113546

DO - 10.3390/molecules181113546

M3 - Journal article

C2 - 24189295

SN - 1420-3049

VL - 18

SP - 13546

EP - 13573

JO - Molecules

JF - Molecules

IS - 11

ER -

Synthesis and thermotropic phase behavior of four glycoglycerolipids

Abstract

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