Determination of sulphur- and chlorine-containing compounds using capillary gas chromatography and atomic emission detection

Stig Pedersen-Bjergaard; Tone Normann Asp; Tyge Greibrokk

doi:10.1016/0003-2670(92)85158-3

Determination of sulphur- and chlorine-containing compounds using capillary gas chromatography and atomic emission detection

Stig Pedersen-Bjergaard, Tone Normann Asp, Tyge Greibrokk^*

^*Corresponding author af dette arbejde

36 Citationer (Scopus)

Abstract

The potential of universal calibration using capillary gas chromatography combined with atomic emission detection was evaluated for several chlorine- and sulphur-containing compounds of environmental interest. The elemental responses obtained for C, H, Cl and S were found to be affected by the molecular structure. Rapid determination of several analytes was accomplished using a single calibration graph based on one randomly selected reference compound, but 10-30% errors relative to the actual concentrations were observed in several instances. The results were significantly improved by using reference compounds with structures similar to those of the analytes of interest. the practical utility of universal calibration is illustrated by the determination of pesticides in stomach oil deposits from birds living in Antarctica.

Originalsprog	Engelsk
Tidsskrift	Analytica Chimica Acta
Vol/bind	265
Udgave nummer	1
Sider (fra-til)	87-92
Antal sider	6
ISSN	0003-2670
DOI	https://doi.org/10.1016/0003-2670(92)85158-3
Status	Udgivet - 1 aug. 1992

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abstract = "The potential of universal calibration using capillary gas chromatography combined with atomic emission detection was evaluated for several chlorine- and sulphur-containing compounds of environmental interest. The elemental responses obtained for C, H, Cl and S were found to be affected by the molecular structure. Rapid determination of several analytes was accomplished using a single calibration graph based on one randomly selected reference compound, but 10-30% errors relative to the actual concentrations were observed in several instances. The results were significantly improved by using reference compounds with structures similar to those of the analytes of interest. the practical utility of universal calibration is illustrated by the determination of pesticides in stomach oil deposits from birds living in Antarctica.",

keywords = "Atomic emission spectrometry, Birds, Chloro compounds, Gas chromatography, Pesticides, Sulphur compounds",

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AU - Pedersen-Bjergaard, Stig

AU - Asp, Tone Normann

AU - Greibrokk, Tyge

PY - 1992/8/1

Y1 - 1992/8/1

N2 - The potential of universal calibration using capillary gas chromatography combined with atomic emission detection was evaluated for several chlorine- and sulphur-containing compounds of environmental interest. The elemental responses obtained for C, H, Cl and S were found to be affected by the molecular structure. Rapid determination of several analytes was accomplished using a single calibration graph based on one randomly selected reference compound, but 10-30% errors relative to the actual concentrations were observed in several instances. The results were significantly improved by using reference compounds with structures similar to those of the analytes of interest. the practical utility of universal calibration is illustrated by the determination of pesticides in stomach oil deposits from birds living in Antarctica.

AB - The potential of universal calibration using capillary gas chromatography combined with atomic emission detection was evaluated for several chlorine- and sulphur-containing compounds of environmental interest. The elemental responses obtained for C, H, Cl and S were found to be affected by the molecular structure. Rapid determination of several analytes was accomplished using a single calibration graph based on one randomly selected reference compound, but 10-30% errors relative to the actual concentrations were observed in several instances. The results were significantly improved by using reference compounds with structures similar to those of the analytes of interest. the practical utility of universal calibration is illustrated by the determination of pesticides in stomach oil deposits from birds living in Antarctica.

KW - Atomic emission spectrometry

KW - Birds

KW - Chloro compounds

KW - Gas chromatography

KW - Pesticides

KW - Sulphur compounds

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DO - 10.1016/0003-2670(92)85158-3

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AN - SCOPUS:0026708048

SN - 0003-2670

VL - 265

SP - 87

EP - 92

JO - Analytica Chimica Acta

JF - Analytica Chimica Acta

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Determination of sulphur- and chlorine-containing compounds using capillary gas chromatography and atomic emission detection

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