Crystal structure of aqua-(2-{[2-({2-[bis-(carboxyl-ato-κ O -meth-yl)amino-κ N ]eth-yl}(carboxyl-ato-κ O -meth-yl)amino-κ N)eth-yl](carb-oxy-meth-yl)aza-niumyl}acetato)-gallium(III) trihydrate

Martin Wallin; Peter Turner; Andrew Katsifis; Mingshi Yang; Hak Kim Chan

doi:10.1107/S2056989018009428

Crystal structure of aqua-(2-{[2-({2-[bis-(carboxyl-ato-κ O -meth-yl)amino-κ N ]eth-yl}(carboxyl-ato-κ O -meth-yl)amino-κ N)eth-yl](carb-oxy-meth-yl)aza-niumyl}acetato)-gallium(III) trihydrate

Martin Wallin, Peter Turner, Andrew Katsifis, Mingshi Yang, Hak Kim Chan^*

^*Corresponding author af dette arbejde

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Abstract

In the title Ga III complex compound with pentetic acid, [Ga(C₁₄ H₂₀ N₃ O₁₀)(H₂ O)]·3H₂ O, the Ga III centre is bound in a slightly distorted octa-hedral coordination sphere by two amine N atoms, three carboxyl-ate O atoms and one water O atom. The complex mol-ecule exists as a zwitterion. In the crystal, the complexes are linked to each other via O - H ... O and C - H ... O hydrogen bonds, forming layers parallel to (001). Three uncoordinating water mol-ecules link the complex layers via O - H ... O, N - H ... O and C - H ... O hydrogen bonds, forming a three-dimensional network.

Originalsprog	Engelsk
Tidsskrift	Acta Crystallographica Section E: Crystallographic Communications
Vol/bind	E74
Sider (fra-til)	1054-1057
ISSN	1600-5368
DOI	https://doi.org/10.1107/S2056989018009428
Status	Udgivet - 2018

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Wallin, M., Turner, P., Katsifis, A., Yang, M., & Chan, H. K. (2018). Crystal structure of aqua-(2-{[2-({2-[bis-(carboxyl-ato-κ O -meth-yl)amino-κ N ]eth-yl}(carboxyl-ato-κ O -meth-yl)amino-κ N)eth-yl](carb-oxy-meth-yl)aza-niumyl}acetato)-gallium(III) trihydrate. Acta Crystallographica Section E: Crystallographic Communications, E74, 1054-1057. https://doi.org/10.1107/S2056989018009428

Crystal structure of aqua-(2-{[2-({2-[bis-(carboxyl-ato-κ O -meth-yl)amino-κ N ]eth-yl}(carboxyl-ato-κ O -meth-yl)amino-κ N)eth-yl](carb-oxy-meth-yl)aza-niumyl}acetato)-gallium(III) trihydrate. / Wallin, Martin; Turner, Peter; Katsifis, Andrew et al.

I: Acta Crystallographica Section E: Crystallographic Communications, Bind E74, 2018, s. 1054-1057.

Publikation: Bidrag til tidsskrift › Tidsskriftartikel › Forskning › peer review

Wallin, M, Turner, P, Katsifis, A, Yang, M & Chan, HK 2018, 'Crystal structure of aqua-(2-{[2-({2-[bis-(carboxyl-ato-κ O -meth-yl)amino-κ N ]eth-yl}(carboxyl-ato-κ O -meth-yl)amino-κ N)eth-yl](carb-oxy-meth-yl)aza-niumyl}acetato)-gallium(III) trihydrate', Acta Crystallographica Section E: Crystallographic Communications, bind E74, s. 1054-1057. https://doi.org/10.1107/S2056989018009428

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title = "Crystal structure of aqua-(2-{[2-({2-[bis-(carboxyl-ato-κ O -meth-yl)amino-κ N ]eth-yl}(carboxyl-ato-κ O -meth-yl)amino-κ N)eth-yl](carb-oxy-meth-yl)aza-niumyl}acetato)-gallium(III) trihydrate",

abstract = "In the title Ga III complex compound with pentetic acid, [Ga(C14 H20 N3 O10)(H2 O)]·3H2 O, the Ga III centre is bound in a slightly distorted octa-hedral coordination sphere by two amine N atoms, three carboxyl-ate O atoms and one water O atom. The complex mol-ecule exists as a zwitterion. In the crystal, the complexes are linked to each other via O - H ... O and C - H ... O hydrogen bonds, forming layers parallel to (001). Three uncoordinating water mol-ecules link the complex layers via O - H ... O, N - H ... O and C - H ... O hydrogen bonds, forming a three-dimensional network.",

keywords = "chelating agents, crystal structure, DTPA, gallium radioisotopes, pentetic acid",

author = "Martin Wallin and Peter Turner and Andrew Katsifis and Mingshi Yang and Chan, {Hak Kim}",

year = "2018",

doi = "10.1107/S2056989018009428",

language = "English",

volume = "E74",

pages = "1054--1057",

journal = "Acta Crystallographica Section E: Structure Reports Online",

issn = "1600-5368",

publisher = "Wiley-Blackwell",

}

TY - JOUR

T1 - Crystal structure of aqua-(2-{[2-({2-[bis-(carboxyl-ato-κ O -meth-yl)amino-κ N ]eth-yl}(carboxyl-ato-κ O -meth-yl)amino-κ N)eth-yl](carb-oxy-meth-yl)aza-niumyl}acetato)-gallium(III) trihydrate

AU - Wallin, Martin

AU - Turner, Peter

AU - Katsifis, Andrew

AU - Yang, Mingshi

AU - Chan, Hak Kim

PY - 2018

Y1 - 2018

N2 - In the title Ga III complex compound with pentetic acid, [Ga(C14 H20 N3 O10)(H2 O)]·3H2 O, the Ga III centre is bound in a slightly distorted octa-hedral coordination sphere by two amine N atoms, three carboxyl-ate O atoms and one water O atom. The complex mol-ecule exists as a zwitterion. In the crystal, the complexes are linked to each other via O - H ... O and C - H ... O hydrogen bonds, forming layers parallel to (001). Three uncoordinating water mol-ecules link the complex layers via O - H ... O, N - H ... O and C - H ... O hydrogen bonds, forming a three-dimensional network.

AB - In the title Ga III complex compound with pentetic acid, [Ga(C14 H20 N3 O10)(H2 O)]·3H2 O, the Ga III centre is bound in a slightly distorted octa-hedral coordination sphere by two amine N atoms, three carboxyl-ate O atoms and one water O atom. The complex mol-ecule exists as a zwitterion. In the crystal, the complexes are linked to each other via O - H ... O and C - H ... O hydrogen bonds, forming layers parallel to (001). Three uncoordinating water mol-ecules link the complex layers via O - H ... O, N - H ... O and C - H ... O hydrogen bonds, forming a three-dimensional network.

KW - chelating agents

KW - crystal structure

KW - DTPA

KW - gallium radioisotopes

KW - pentetic acid

UR - http://www.scopus.com/inward/record.url?scp=85051114700&partnerID=8YFLogxK

U2 - 10.1107/S2056989018009428

DO - 10.1107/S2056989018009428

M3 - Journal article

C2 - 30116560

AN - SCOPUS:85051114700

SN - 1600-5368

VL - E74

SP - 1054

EP - 1057

JO - Acta Crystallographica Section E: Structure Reports Online

JF - Acta Crystallographica Section E: Structure Reports Online

ER -

Crystal structure of aqua-(2-{[2-({2-[bis-(carboxyl-ato-κ O -meth-yl)amino-κ N ]eth-yl}(carboxyl-ato-κ O -meth-yl)amino-κ N)eth-yl](carb-oxy-meth-yl)aza-niumyl}acetato)-gallium(III) trihydrate

Abstract

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