TY - JOUR
T1 - Capillary gas chromatography coupled with negative ionization microplasma mass spectrometry for halogen-selective detection
AU - Brede, Cato
AU - Pedersen-Bjergaard, Stig
AU - Lundanes, Elsa
AU - Greibrokk, Tyge
PY - 2000/1/1
Y1 - 2000/1/1
N2 - Gas chromatography was coupled with plasma mass spectrometry with a microplasma ion source for negative ion detection. The ion source, which was kept inside the high vacuum chamber of the mass spectrometer, was a rigid fused silica capillary tube containing a capacitively coupled radiofrequency helium plasma. This made the setup quite simple: eliminating the sampler-skimmer pressure-reducing interface traditionally used in plasma mass spectrometry. The present study describes the utilization of halogen-selective negative ion detection. A high selectivity of fluorine to hydrocarbon compounds (3×103), and a highly sensitive detection for F, Cl, Br, and I (0.13-12 pg s-1), were obtained. The mechanisms of negative ion formation and breakdown were discussed in conjunction with the results that were achieved.
AB - Gas chromatography was coupled with plasma mass spectrometry with a microplasma ion source for negative ion detection. The ion source, which was kept inside the high vacuum chamber of the mass spectrometer, was a rigid fused silica capillary tube containing a capacitively coupled radiofrequency helium plasma. This made the setup quite simple: eliminating the sampler-skimmer pressure-reducing interface traditionally used in plasma mass spectrometry. The present study describes the utilization of halogen-selective negative ion detection. A high selectivity of fluorine to hydrocarbon compounds (3×103), and a highly sensitive detection for F, Cl, Br, and I (0.13-12 pg s-1), were obtained. The mechanisms of negative ion formation and breakdown were discussed in conjunction with the results that were achieved.
UR - http://www.scopus.com/inward/record.url?scp=0033879153&partnerID=8YFLogxK
U2 - 10.1039/a904211c
DO - 10.1039/a904211c
M3 - Journal article
AN - SCOPUS:0033879153
SN - 0267-9477
VL - 15
SP - 55
EP - 60
JO - Journal of Analytical Atomic Spectrometry
JF - Journal of Analytical Atomic Spectrometry
IS - 1
ER -