Application of hollow cylindrical wheat stem for electromembrane extraction of thorium in water samples

Mostafa Khajeh; Stig Pedersen-Bjergaard; Afsaneh Barkhordar; Mousa Bahlooli

doi:10.1016/j.saa.2014.08.103

Application of hollow cylindrical wheat stem for electromembrane extraction of thorium in water samples

Mostafa Khajeh, Stig Pedersen-Bjergaard, Afsaneh Barkhordar, Mousa Bahlooli

20 Citationer (Scopus)

Abstract

In this study, wheat stem was used for electromembrane extraction (EME) for the first time. The EME technique involved the use of a wheat stem whose channel was filled with 3 M HCl, immersed in 10 mL of an aqueous sample solution. Thorium migrated from aqueous samples, through a thin layer of 1-octanol and 5%v/v Di-(2-ethylhexyl) phosphate (DEHP) immobilized in the pores of a porous stem, and into an acceptor phase solution present inside the lumen of the stem. The pH of donor and acceptor phases, extraction time, voltage, and stirring speed were optimized. At the optimum conditions, an enrichment factor of 50 and a limit of detection of 0.29 ng mL1 was obtained for thorium. The developed
procedure was then applied to the extraction and determination of thorium in water samples and in reference material.

Originalsprog	Engelsk
Tidsskrift	Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy
Vol/bind	137
Sider (fra-til)	328-332
Antal sider	5
ISSN	1386-1425
DOI	https://doi.org/10.1016/j.saa.2014.08.103
Status	Udgivet - 25 feb. 2015

Adgang til dokumentet

10.1016/j.saa.2014.08.103

Citationsformater

@article{e4f36e5bf2c24d6882110f4e419df3c3,

title = "Application of hollow cylindrical wheat stem for electromembrane extraction of thorium in water samples",

abstract = "In this study, wheat stem was used for electromembrane extraction (EME) for the first time. The EME technique involved the use of a wheat stem whose channel was filled with 3 M HCl, immersed in 10 mL of an aqueous sample solution. Thorium migrated from aqueous samples, through a thin layer of 1-octanol and 5%v/v Di-(2-ethylhexyl) phosphate (DEHP) immobilized in the pores of a porous stem, and into an acceptor phase solution present inside the lumen of the stem. The pH of donor and acceptor phases, extraction time, voltage, and stirring speed were optimized. At the optimum conditions, an enrichment factor of 50 and a limit of detection of 0.29 ng mL1 was obtained for thorium. The developedprocedure was then applied to the extraction and determination of thorium in water samples and in reference material.",

author = "Mostafa Khajeh and Stig Pedersen-Bjergaard and Afsaneh Barkhordar and Mousa Bahlooli",

year = "2015",

month = feb,

day = "25",

doi = "10.1016/j.saa.2014.08.103",

language = "English",

volume = "137",

pages = "328--332",

journal = "Spectrochimica Acta - Part A: Molecular and Biomolecular Spectroscopy",

issn = "1386-1425",

publisher = "Elsevier",

}

TY - JOUR

T1 - Application of hollow cylindrical wheat stem for electromembrane extraction of thorium in water samples

AU - Khajeh, Mostafa

AU - Pedersen-Bjergaard, Stig

AU - Barkhordar, Afsaneh

AU - Bahlooli, Mousa

PY - 2015/2/25

Y1 - 2015/2/25

N2 - In this study, wheat stem was used for electromembrane extraction (EME) for the first time. The EME technique involved the use of a wheat stem whose channel was filled with 3 M HCl, immersed in 10 mL of an aqueous sample solution. Thorium migrated from aqueous samples, through a thin layer of 1-octanol and 5%v/v Di-(2-ethylhexyl) phosphate (DEHP) immobilized in the pores of a porous stem, and into an acceptor phase solution present inside the lumen of the stem. The pH of donor and acceptor phases, extraction time, voltage, and stirring speed were optimized. At the optimum conditions, an enrichment factor of 50 and a limit of detection of 0.29 ng mL1 was obtained for thorium. The developedprocedure was then applied to the extraction and determination of thorium in water samples and in reference material.

AB - In this study, wheat stem was used for electromembrane extraction (EME) for the first time. The EME technique involved the use of a wheat stem whose channel was filled with 3 M HCl, immersed in 10 mL of an aqueous sample solution. Thorium migrated from aqueous samples, through a thin layer of 1-octanol and 5%v/v Di-(2-ethylhexyl) phosphate (DEHP) immobilized in the pores of a porous stem, and into an acceptor phase solution present inside the lumen of the stem. The pH of donor and acceptor phases, extraction time, voltage, and stirring speed were optimized. At the optimum conditions, an enrichment factor of 50 and a limit of detection of 0.29 ng mL1 was obtained for thorium. The developedprocedure was then applied to the extraction and determination of thorium in water samples and in reference material.

U2 - 10.1016/j.saa.2014.08.103

DO - 10.1016/j.saa.2014.08.103

M3 - Journal article

SN - 1386-1425

VL - 137

SP - 328

EP - 332

JO - Spectrochimica Acta - Part A: Molecular and Biomolecular Spectroscopy

JF - Spectrochimica Acta - Part A: Molecular and Biomolecular Spectroscopy

ER -

Application of hollow cylindrical wheat stem for electromembrane extraction of thorium in water samples

Abstract

Adgang til dokumentet

Fingeraftryk

Citationsformater