Water sorption in wood and modified wood at high values of relative humidity. Part I: Results for untreated, acetylated, and furfurylated Norway spruce

TY - JOUR

T1 - Water sorption in wood and modified wood at high values of relative humidity. Part I: Results for untreated, acetylated, and furfurylated Norway spruce

AU - Thygesen, Lisbeth Garbrecht

AU - Engelund, Emil Tang

AU - Hoffmeyer, Preben

PY - 2010/4/1

Y1 - 2010/4/1

N2 - Desorption isotherms at 20° C for untreated, acetylated, and furfurylated Norway spruce [Picea abies (L.) Karst.] sapwood were established in the 91.9-99.9% relative humidity (RH) range. Three methods were employed to secure various constant RH levels: saturated salt solutions, climate chambers, and the pressure plate technique. The curve form for the untreated samples did not show an upward bend, except perhaps above 99.5% RH, indicating that - contrary to what has hitherto been assumed - capillary condensation does not play a significant role for water sorption in wood below fiber saturation. Three additional results corroborate this conclusion: (1) calculation of the theoretical contribution of capillary condensation to the moisture content (MC) in wood based on idealized microstructural geometries by means of the Kelvin and Laplace equations resulted in very small contributions to the equilibrium moisture content (EMC), i.e., below 0.35% moisture at 99.9% RH. (2) The ratio between the EMC of acetylated and untreated samples did not show an increasing trend for increasing RH, as would have been the case if capillary condensation had taken place in both untreated and acetylated wood. (3) Low field time domain nuclear magnetic resonance results showed that only the relaxation curves from the furfurylated samples were affected systematically by freezing, indicating that neither untreated nor acetylated wood contained significant amounts of capillary condensed water.

AB - Desorption isotherms at 20° C for untreated, acetylated, and furfurylated Norway spruce [Picea abies (L.) Karst.] sapwood were established in the 91.9-99.9% relative humidity (RH) range. Three methods were employed to secure various constant RH levels: saturated salt solutions, climate chambers, and the pressure plate technique. The curve form for the untreated samples did not show an upward bend, except perhaps above 99.5% RH, indicating that - contrary to what has hitherto been assumed - capillary condensation does not play a significant role for water sorption in wood below fiber saturation. Three additional results corroborate this conclusion: (1) calculation of the theoretical contribution of capillary condensation to the moisture content (MC) in wood based on idealized microstructural geometries by means of the Kelvin and Laplace equations resulted in very small contributions to the equilibrium moisture content (EMC), i.e., below 0.35% moisture at 99.9% RH. (2) The ratio between the EMC of acetylated and untreated samples did not show an increasing trend for increasing RH, as would have been the case if capillary condensation had taken place in both untreated and acetylated wood. (3) Low field time domain nuclear magnetic resonance results showed that only the relaxation curves from the furfurylated samples were affected systematically by freezing, indicating that neither untreated nor acetylated wood contained significant amounts of capillary condensed water.

U2 - 10.1515/hf.2010.044

DO - 10.1515/hf.2010.044

M3 - Journal article

SN - 0018-3830

VL - 64

SP - 315

EP - 323

JO - Holzforschung

JF - Holzforschung

IS - 3

ER -