TY - JOUR
T1 - Ultraviolet absorption spectra and kinetics of CH3S and CH2SH radicals
AU - Anastasi, Christopher
AU - Broomfield, Mark
AU - Nielsen, Ole John
AU - Pagsberg, Palle
PY - 1991/8/16
Y1 - 1991/8/16
N2 - The ultraviolet absorption spectra of CH3S and CH2SH radicals have been measured between 215 and 380 nm using the pulse-radiolysis/kinetic-abso method. One absorption band between 250 and 300 nm and one around 215 nm have been tentatively assigned to the CH2SH and CH3S radicals, respectively. This spectrum has been used to measure the self-reaction rates of these radicals. Rate constants of 4 × 10-11 and 7 × 10-11 cm3 molecule-1 s-1 have been measured at 298 K for CH3S and CH2SH recombination, respectively. The possible reaction pathways are discussed.
AB - The ultraviolet absorption spectra of CH3S and CH2SH radicals have been measured between 215 and 380 nm using the pulse-radiolysis/kinetic-abso method. One absorption band between 250 and 300 nm and one around 215 nm have been tentatively assigned to the CH2SH and CH3S radicals, respectively. This spectrum has been used to measure the self-reaction rates of these radicals. Rate constants of 4 × 10-11 and 7 × 10-11 cm3 molecule-1 s-1 have been measured at 298 K for CH3S and CH2SH recombination, respectively. The possible reaction pathways are discussed.
UR - http://www.scopus.com/inward/record.url?scp=4243811299&partnerID=8YFLogxK
U2 - 10.1016/0009-2614(91)90139-Z
DO - 10.1016/0009-2614(91)90139-Z
M3 - Journal article
AN - SCOPUS:4243811299
SN - 0009-2614
VL - 182
SP - 643
EP - 648
JO - Chemical Physics Letters
JF - Chemical Physics Letters
IS - 6
ER -