The importance of being porous: Polysaccharide-derived mesoporous materials for use in dye adsorption

Helen L. Parker; Andrew J. Hunt; Vitaly L. Budarin; Peter S. Shuttleworth; Kathryn L. Miller; James H. Clark

doi:10.1039/c2ra21367b

The importance of being porous: Polysaccharide-derived mesoporous materials for use in dye adsorption

Helen L. Parker, Andrew J. Hunt^*, Vitaly L. Budarin, Peter S. Shuttleworth, Kathryn L. Miller, James H. Clark

^*Corresponding author for this work

104 Citations (Scopus)

Abstract

The controlled pyrolysis of mesoporous polysaccharide-derived materials, from starch and alginic acid, formed carbonaceous materials (Starbons ^®) and were demonstrated as efficient materials for the removal of dyes from wastewater. The resulting materials were characterised by solid-state NMR, N₂ adsorption porosimetry, FT-IR, scanning electron microscopy (SEM) and tunnelling electron microscopy (TEM). The material's efficiency for dye adsorption was tested using methylene blue (MB) and acid blue 92 (AB) dyes. Adsorption data indicated that the mesoporosity of the material had a far greater influence on the adsorption capacity and speed of adsorption, than high surface area alone. Mesoporous Starbon^® (A300) was evaluated against commercially available activated carbon (Norit) and demonstrated a superior adsorption capacity of MB; 186 mg g^-1vs. 42 mg g^-1. The kinetic activity of Starbon^® was also determined with A800 showing the fastest rate of adsorption compared to S800 and Norit, suggesting that it is a more suitable material for water purification.

Original language	English
Journal	RSC Advances
Volume	2
Issue number	24
Pages (from-to)	8992-8997
Number of pages	6
ISSN	2046-2069
DOIs	https://doi.org/10.1039/c2ra21367b
Publication status	Published - 19 Dec 2012

Access to Document

10.1039/c2ra21367b

Cite this

@article{2dc57524c5de4c88b08c7e579d82e123,

title = "The importance of being porous: Polysaccharide-derived mesoporous materials for use in dye adsorption",

abstract = "The controlled pyrolysis of mesoporous polysaccharide-derived materials, from starch and alginic acid, formed carbonaceous materials (Starbons {\textregistered}) and were demonstrated as efficient materials for the removal of dyes from wastewater. The resulting materials were characterised by solid-state NMR, N2 adsorption porosimetry, FT-IR, scanning electron microscopy (SEM) and tunnelling electron microscopy (TEM). The material's efficiency for dye adsorption was tested using methylene blue (MB) and acid blue 92 (AB) dyes. Adsorption data indicated that the mesoporosity of the material had a far greater influence on the adsorption capacity and speed of adsorption, than high surface area alone. Mesoporous Starbon{\textregistered} (A300) was evaluated against commercially available activated carbon (Norit) and demonstrated a superior adsorption capacity of MB; 186 mg g-1vs. 42 mg g-1. The kinetic activity of Starbon{\textregistered} was also determined with A800 showing the fastest rate of adsorption compared to S800 and Norit, suggesting that it is a more suitable material for water purification.",

author = "Parker, {Helen L.} and Hunt, {Andrew J.} and Budarin, {Vitaly L.} and Shuttleworth, {Peter S.} and Miller, {Kathryn L.} and Clark, {James H.}",

year = "2012",

month = dec,

day = "19",

doi = "10.1039/c2ra21367b",

language = "English",

volume = "2",

pages = "8992--8997",

journal = "RSC Advances",

issn = "2046-2069",

publisher = "RSC Publishing",

number = "24",

}

TY - JOUR

T1 - The importance of being porous

T2 - Polysaccharide-derived mesoporous materials for use in dye adsorption

AU - Parker, Helen L.

AU - Hunt, Andrew J.

AU - Budarin, Vitaly L.

AU - Shuttleworth, Peter S.

AU - Miller, Kathryn L.

AU - Clark, James H.

PY - 2012/12/19

Y1 - 2012/12/19

N2 - The controlled pyrolysis of mesoporous polysaccharide-derived materials, from starch and alginic acid, formed carbonaceous materials (Starbons ®) and were demonstrated as efficient materials for the removal of dyes from wastewater. The resulting materials were characterised by solid-state NMR, N2 adsorption porosimetry, FT-IR, scanning electron microscopy (SEM) and tunnelling electron microscopy (TEM). The material's efficiency for dye adsorption was tested using methylene blue (MB) and acid blue 92 (AB) dyes. Adsorption data indicated that the mesoporosity of the material had a far greater influence on the adsorption capacity and speed of adsorption, than high surface area alone. Mesoporous Starbon® (A300) was evaluated against commercially available activated carbon (Norit) and demonstrated a superior adsorption capacity of MB; 186 mg g-1vs. 42 mg g-1. The kinetic activity of Starbon® was also determined with A800 showing the fastest rate of adsorption compared to S800 and Norit, suggesting that it is a more suitable material for water purification.

AB - The controlled pyrolysis of mesoporous polysaccharide-derived materials, from starch and alginic acid, formed carbonaceous materials (Starbons ®) and were demonstrated as efficient materials for the removal of dyes from wastewater. The resulting materials were characterised by solid-state NMR, N2 adsorption porosimetry, FT-IR, scanning electron microscopy (SEM) and tunnelling electron microscopy (TEM). The material's efficiency for dye adsorption was tested using methylene blue (MB) and acid blue 92 (AB) dyes. Adsorption data indicated that the mesoporosity of the material had a far greater influence on the adsorption capacity and speed of adsorption, than high surface area alone. Mesoporous Starbon® (A300) was evaluated against commercially available activated carbon (Norit) and demonstrated a superior adsorption capacity of MB; 186 mg g-1vs. 42 mg g-1. The kinetic activity of Starbon® was also determined with A800 showing the fastest rate of adsorption compared to S800 and Norit, suggesting that it is a more suitable material for water purification.

UR - http://www.scopus.com/inward/record.url?scp=84871070234&partnerID=8YFLogxK

U2 - 10.1039/c2ra21367b

DO - 10.1039/c2ra21367b

M3 - Journal article

AN - SCOPUS:84871070234

SN - 2046-2069

VL - 2

SP - 8992

EP - 8997

JO - RSC Advances

JF - RSC Advances

IS - 24

ER -

The importance of being porous: Polysaccharide-derived mesoporous materials for use in dye adsorption

Abstract

Access to Document

Other files and links

Fingerprint

Cite this