The importance of being exchanged: [Gd^III₄M^II₈(OH)₈(L)₈(O₂CR)₈]⁴⁺ clusters for magnetic refrigeration

TY - JOUR

T1 - The importance of being exchanged

T2 - [GdIII4MII8(OH)8(L)8(O2CR)8]4+ clusters for magnetic refrigeration

AU - Hooper, Thomas N.

AU - Schnack, Jürgen

AU - Piligkos, Stergios

AU - Evangelisti, Marco

AU - Brechin, Euan K.

PY - 2012/5/7

Y1 - 2012/5/7

N2 - Playing it cool: Almost all of the constituent parts of the complex [Ln III 4M II 8(OH) 8(L) 8(O 2CR) 8]X 4, namely the lanthanide ions Ln 3+, the transition-metal ions M 2+, the bridging ligand L, the carboxylates, and the counterions X can be exchanged, thus allowing a thorough understanding of the individual contributions to the magnetocaloric effect. Example in picture: Gd purple, Cu green, O red, N blue.

AB - Playing it cool: Almost all of the constituent parts of the complex [Ln III 4M II 8(OH) 8(L) 8(O 2CR) 8]X 4, namely the lanthanide ions Ln 3+, the transition-metal ions M 2+, the bridging ligand L, the carboxylates, and the counterions X can be exchanged, thus allowing a thorough understanding of the individual contributions to the magnetocaloric effect. Example in picture: Gd purple, Cu green, O red, N blue.

U2 - 10.1002/anie.201200072

DO - 10.1002/anie.201200072

M3 - Journal article

C2 - 22473842

SN - 1433-7851

VL - 51

SP - 4633

EP - 4636

JO - Angewandte Chemie International Edition

JF - Angewandte Chemie International Edition

IS - 19

ER -