The effect of particle size and ligand configuration on the asymmetric catalytic properties of proline-functionalized Pt-nanoparticles

Imke Schrader; Sarah Neumann; Rieke Himstedt; Alessandro Zana; Jonas Warneke; Sebastian Kunz

doi:10.1039/c5cc06990d

The effect of particle size and ligand configuration on the asymmetric catalytic properties of proline-functionalized Pt-nanoparticles

Imke Schrader, Sarah Neumann, Rieke Himstedt, Alessandro Zana, Jonas Warneke, Sebastian Kunz

Department of Chemistry

23 Citations (Scopus)

Abstract

The effect of particle size on the asymmetric catalytic properties of supported ligand-functionalized nanoparticles (NPs) was investigated for the first time and found to alter significantly the activity but surprisingly not the stereoselectivity. These results suggest that the stereoselectivity of these complex systems is primarily determined by the ligand-reactant interaction, whereas the activity is determined by the particle size.

Original language	English
Journal	Chemical Communications
Volume	51
Issue number	90
Pages (from-to)	16221-16224
Number of pages	4
ISSN	1359-7345
DOIs	https://doi.org/10.1039/c5cc06990d
Publication status	Published - 2015

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title = "The effect of particle size and ligand configuration on the asymmetric catalytic properties of proline-functionalized Pt-nanoparticles",

abstract = "The effect of particle size on the asymmetric catalytic properties of supported ligand-functionalized nanoparticles (NPs) was investigated for the first time and found to alter significantly the activity but surprisingly not the stereoselectivity. These results suggest that the stereoselectivity of these complex systems is primarily determined by the ligand-reactant interaction, whereas the activity is determined by the particle size.",

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T1 - The effect of particle size and ligand configuration on the asymmetric catalytic properties of proline-functionalized Pt-nanoparticles

AU - Schrader, Imke

AU - Neumann, Sarah

AU - Himstedt, Rieke

AU - Zana, Alessandro

AU - Warneke, Jonas

AU - Kunz, Sebastian

PY - 2015

Y1 - 2015

N2 - The effect of particle size on the asymmetric catalytic properties of supported ligand-functionalized nanoparticles (NPs) was investigated for the first time and found to alter significantly the activity but surprisingly not the stereoselectivity. These results suggest that the stereoselectivity of these complex systems is primarily determined by the ligand-reactant interaction, whereas the activity is determined by the particle size.

AB - The effect of particle size on the asymmetric catalytic properties of supported ligand-functionalized nanoparticles (NPs) was investigated for the first time and found to alter significantly the activity but surprisingly not the stereoselectivity. These results suggest that the stereoselectivity of these complex systems is primarily determined by the ligand-reactant interaction, whereas the activity is determined by the particle size.

U2 - 10.1039/c5cc06990d

DO - 10.1039/c5cc06990d

M3 - Letter

C2 - 26399500

SN - 1359-7345

VL - 51

SP - 16221

EP - 16224

JO - Chemical Communications

JF - Chemical Communications

IS - 90

ER -

The effect of particle size and ligand configuration on the asymmetric catalytic properties of proline-functionalized Pt-nanoparticles

Abstract

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