Ternary self-assemblies in water: forming a pentanuclear ReLn₄ assembly by association of binuclear lanthanide binding pockets with fac-Re(CO)₃(dinicotinate)₂Cl

TY - JOUR

T1 - Ternary self-assemblies in water

T2 - forming a pentanuclear ReLn4 assembly by association of binuclear lanthanide binding pockets with fac-Re(CO)3(dinicotinate)2Cl

AU - Hill, Leila R.

AU - Blackburn, Octavia A.

AU - Jones, Michael W.

AU - Tropiano, Manuel

AU - Sørensen, Thomas Just

AU - Faulkner, Stephen

PY - 2013/12/14

Y1 - 2013/12/14

N2 - The self-assembly of higher order structures in water is realised by using the association of 1,3-biscarboxylates to binuclear meta-xylyl bridged DO3A complexes. Two dinicotinate binding sites are placed at a right-angle in a rhenium complex, which is shown to form a 1 : 2 complex with α,α'-bis(Eu·DO3A)-5-amino-m-xylene.

AB - The self-assembly of higher order structures in water is realised by using the association of 1,3-biscarboxylates to binuclear meta-xylyl bridged DO3A complexes. Two dinicotinate binding sites are placed at a right-angle in a rhenium complex, which is shown to form a 1 : 2 complex with α,α'-bis(Eu·DO3A)-5-amino-m-xylene.

U2 - 10.1039/c3dt51705e

DO - 10.1039/c3dt51705e

M3 - Journal article

C2 - 23939285

SN - 1477-9226

VL - 42

SP - 16255

EP - 16258

JO - Acta chemica Scandinavica. Series A: Physical and inorganic chemistry

JF - Acta chemica Scandinavica. Series A: Physical and inorganic chemistry

IS - 46

ER -