Synthons for carbide complex chemistry

Anders Reinholdt; Anthony F.  Hill; Jesper Bendix

Synthons for carbide complex chemistry

Anders Reinholdt, Anthony F. Hill, Jesper Bendix

Department of Chemistry

14 Citations (Scopus)

Abstract

The sterically accessible carbide complex, (Cy₃P)Cl₃RuC-PtCl(py)₂, acts as a synthon for terminal and bridging carbide fragments that relocate to pincer and A-frame scaffolds upon ligand addition. This concept, benefitting from coordination sphere selection as the concluding step, confronts traditional synthetic strategies and broadens the scope for carbide complexes.

Original language	English
Journal	Chemical Communications
Volume	54
Pages (from-to)	5708-5711
Number of pages	4
ISSN	1359-7345
Publication status	Published - 2018

Cite this

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title = "Synthons for carbide complex chemistry",

abstract = "The sterically accessible carbide complex, (Cy3P)Cl3RuC-PtCl(py)2, acts as a synthon for terminal and bridging carbide fragments that relocate to pincer and A-frame scaffolds upon ligand addition. This concept, benefitting from coordination sphere selection as the concluding step, confronts traditional synthetic strategies and broadens the scope for carbide complexes.",

author = "Anders Reinholdt and Hill, {Anthony F.} and Jesper Bendix",

year = "2018",

language = "English",

volume = "54",

pages = "5708--5711",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

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TY - JOUR

T1 - Synthons for carbide complex chemistry

AU - Reinholdt, Anders

AU - Hill, Anthony F.

AU - Bendix, Jesper

PY - 2018

Y1 - 2018

N2 - The sterically accessible carbide complex, (Cy3P)Cl3RuC-PtCl(py)2, acts as a synthon for terminal and bridging carbide fragments that relocate to pincer and A-frame scaffolds upon ligand addition. This concept, benefitting from coordination sphere selection as the concluding step, confronts traditional synthetic strategies and broadens the scope for carbide complexes.

AB - The sterically accessible carbide complex, (Cy3P)Cl3RuC-PtCl(py)2, acts as a synthon for terminal and bridging carbide fragments that relocate to pincer and A-frame scaffolds upon ligand addition. This concept, benefitting from coordination sphere selection as the concluding step, confronts traditional synthetic strategies and broadens the scope for carbide complexes.

M3 - Journal article

SN - 1359-7345

VL - 54

SP - 5708

EP - 5711

JO - Chemical Communications

JF - Chemical Communications

ER -

Synthons for carbide complex chemistry

Abstract

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