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Secondary kinetic deuterium isotope effects. The CC cleavage of. labeled tetramethylethylenediamine radical cations-Who gets to keep the electron?
Christian Bech Nielsen, Steen Hammerum
Department of Chemistry
3
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Dive into the research topics of 'Secondary kinetic deuterium isotope effects. The CC cleavage of. labeled tetramethylethylenediamine radical cations-Who gets to keep the electron?'. Together they form a unique fingerprint.
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Physics & Astronomy
isotope effect
75%
cleavage
71%
deuterium
64%
cations
58%
vibration
45%
zero point energy
44%
products
44%
kinetics
41%
amines
40%
molecular ions
38%
retaining
38%
methylidyne
34%
dimers
31%
fragments
29%
electrons
29%
dissociation
28%
analogs
27%
shift
21%
interactions
13%
energy
10%
Chemical Compounds
Isotope Effect
71%
Deuterium(.)
63%
Transition State
57%
Zero-Point Vibrational Energy
50%
Cleavage
47%
Zero Point Energy
46%
Kinetic Isotope Effect
38%
Electron Particle
37%
Stretching Vibration
36%
Molecular Ion
36%
Methyl Group
29%
Dissociation
24%
Amine
22%
Reaction Yield
14%
Engineering & Materials Science
Deuterium
100%
Positive ions
86%
Isotopes
85%
Electrons
69%
Dimers
52%
Amines
41%
Stretching
36%
Ions
31%