Predicting transport regime and local electrostatic environment from Coulomb blockade diamond sizes

TY - JOUR

T1 - Predicting transport regime and local electrostatic environment from Coulomb blockade diamond sizes

AU - Olsen, Stine Tetzschner

AU - Hansen, Thorsten

AU - Mikkelsen, Kurt Valentin

PY - 2017

Y1 - 2017

N2 - Electron transport through a molecule is often described in one of the two regimes: the coherent tunnelling regime or the Coulomb blockade regime. The twilight zone of the two regimes still possesses many unsolved questions. A theoretical analysis of the oligophenylenevinylene OPV3 experiments by Bjørnholm and co-workers is performed. The experiments showed how two OPV3 derivatives performed very differently despite the strong similarity of the molecular structure, hence the experimental data showed two different transport mechanisms. The different transport mechanisms of the two OPV3 derivatives are explained from quantum mechanical calculations of the molecular redox energies and from the experimentally accessible window size.

AB - Electron transport through a molecule is often described in one of the two regimes: the coherent tunnelling regime or the Coulomb blockade regime. The twilight zone of the two regimes still possesses many unsolved questions. A theoretical analysis of the oligophenylenevinylene OPV3 experiments by Bjørnholm and co-workers is performed. The experiments showed how two OPV3 derivatives performed very differently despite the strong similarity of the molecular structure, hence the experimental data showed two different transport mechanisms. The different transport mechanisms of the two OPV3 derivatives are explained from quantum mechanical calculations of the molecular redox energies and from the experimentally accessible window size.

U2 - 10.1063/1.4978243

DO - 10.1063/1.4978243

M3 - Journal article

C2 - 28298124

AN - SCOPUS:85015221243

SN - 0021-9606

VL - 146

JO - Journal of Chemical Physics

JF - Journal of Chemical Physics

IS - 10

M1 - 104306

ER -