Platinum(ii) as an assembly point for carbide and nitride ligands

Anders Reinholdt; Jesper Bendix

doi:10.1039/c9cc03411k

Platinum(ii) as an assembly point for carbide and nitride ligands

Anders Reinholdt, Jesper Bendix

Department of Chemistry

3 Citations (Scopus)

Abstract

The sequential treatment of (Cy₃P)₂Cl₂RuC with [PtCl₂(C₂H₄)]₂ and (dbm)₂CrN affords trans-(Cy₃P)₂Cl₂RuC-PtCl₂-NCr(dbm)₂, in which a platinum(ii) center is coordinated by both carbide and nitride ligands. ESR spectroscopy indicates that the carbide-nitride complex is loosely associated and that its unpaired electron remains localized mainly at the chromium center.

Original language	English
Journal	Chemical Communications
Volume	55
Issue number	57
Pages (from-to)	8270-8273
ISSN	1359-7345
DOIs	https://doi.org/10.1039/c9cc03411k
Publication status	Published - 2019

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title = "Platinum(ii) as an assembly point for carbide and nitride ligands",

abstract = "The sequential treatment of (Cy3P)2Cl2RuC with [PtCl2(C2H4)]2 and (dbm)2CrN affords trans-(Cy3P)2Cl2RuC-PtCl2-NCr(dbm)2, in which a platinum(ii) center is coordinated by both carbide and nitride ligands. ESR spectroscopy indicates that the carbide-nitride complex is loosely associated and that its unpaired electron remains localized mainly at the chromium center.",

author = "Anders Reinholdt and Jesper Bendix",

year = "2019",

doi = "10.1039/c9cc03411k",

language = "English",

volume = "55",

pages = "8270--8273",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

number = "57",

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TY - JOUR

T1 - Platinum(ii) as an assembly point for carbide and nitride ligands

AU - Reinholdt, Anders

AU - Bendix, Jesper

PY - 2019

Y1 - 2019

N2 - The sequential treatment of (Cy3P)2Cl2RuC with [PtCl2(C2H4)]2 and (dbm)2CrN affords trans-(Cy3P)2Cl2RuC-PtCl2-NCr(dbm)2, in which a platinum(ii) center is coordinated by both carbide and nitride ligands. ESR spectroscopy indicates that the carbide-nitride complex is loosely associated and that its unpaired electron remains localized mainly at the chromium center.

AB - The sequential treatment of (Cy3P)2Cl2RuC with [PtCl2(C2H4)]2 and (dbm)2CrN affords trans-(Cy3P)2Cl2RuC-PtCl2-NCr(dbm)2, in which a platinum(ii) center is coordinated by both carbide and nitride ligands. ESR spectroscopy indicates that the carbide-nitride complex is loosely associated and that its unpaired electron remains localized mainly at the chromium center.

U2 - 10.1039/c9cc03411k

DO - 10.1039/c9cc03411k

M3 - Journal article

C2 - 31246199

SN - 1359-7345

VL - 55

SP - 8270

EP - 8273

JO - Chemical Communications

JF - Chemical Communications

IS - 57

ER -

Platinum(ii) as an assembly point for carbide and nitride ligands

Abstract

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