pH matters: The influence of the catalyst ink on the oxygen reduction activity determined in thin film rotating disk electrode measurements

Masanori Inaba, Jonathan Quinson, Matthias Arenz*

*Corresponding author for this work
25 Citations (Scopus)

Abstract

We investigated the influence of the ink properties of proton exchange membrane fuel cell (PEMFC) catalysts on the oxygen reduction reaction (ORR) activity determined in thin film rotating disk electrode (TF-RDE) measurements. It was found that the adaption of a previously reported ink recipe to home-made catalysts does not lead to satisfying results, although reported work could be reproduced using commercial catalyst samples. It is demonstrated that the pH of the catalyst ink, which has not been addressed in previous TF-RDE studies, is an important parameter that needs to be carefully controlled to determine the intrinsic ORR activity of high surface area catalysts.

Original languageEnglish
JournalJournal of Power Sources
Volume353
Pages (from-to)19-27
Number of pages9
ISSN0378-7753
DOIs
Publication statusPublished - 2017

Keywords

  • Carbon supported catalyst
  • Catalyst ink
  • Oxygen reduction reaction
  • Platinum
  • Rotating disc electrode

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