Oskarssonite, AlF3, a new fumarolic mineral from Eldfell volcano, Heimaey, Iceland.

Morten Jølnæs Jacobsen; Tonci Balic Zunic; Donatella Mitolo; Anna Katerinopoulou; Anna Garavelli; Sveinn Peter Jakobsson

doi:10.1180/minmag.2014.078.1.15

Oskarssonite, AlF3, a new fumarolic mineral from Eldfell volcano, Heimaey, Iceland.

Morten Jølnæs Jacobsen, Tonci Balic Zunic, Donatella Mitolo, Anna Katerinopoulou, Anna Garavelli, Sveinn Peter Jakobsson

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Abstract

The new mineral oskarssonite (IMA2012-088), with ideal formula AlF3, was found in August 2009 at the surface of fumaroles on the Eldfell volcano, Heimaey Island, Iceland (GPS coordinates 63°25'58.9"N 20°14'50.3"W). It occurs as sub-micron-sized crystals forming a white powder in association with anhydrite, bassanite, gypsum, jarosite, anatase, hematite, opal, ralstonite, jakobssonite and meniaylovite. Chemical analyses by energy-dispersive spectrometry with a scanning electronmicroscope produced the following mean elemental composition: Al, 31.70; F, 58.41; O, 9.22; total 99.33 wt.%. The empirical chemical formula is AlF2.6(OH)0.5 which suggests partial substitution of F by OH. Oskarssonite is rhombohedral, space group R3- c, with ah = 4.9817(4) Å , c = 12.387(1) Å , Vuc = 266.23(5) Å 3, Z = 6. The five strongest lines in the powder diffraction diagram [d in Å (I) (hkl)] are as follows: 3.54 (100) (012), 2.131 (13) (113), 1.771 (20) (024), 1.59 (15) (116), 1.574 (10) (122). Rietveld refinement confirms the identity of oskarssonite with the synthetic rhombohedral form of AlF3. Its structure can be described as a rhombohedral deformation of the idealized cubic perovskitetype octahedral framework of corner-sharing AlF6 groups. Oskarssonite appears in the surface part of the fumaroles where fluorides are abundant. At greater depths (below 10 cm) sulfates dominate among the fumarolic minerals. In accordance with its occurrence, we surmise that oskarssonite forms in the later stages of the fumarolic activity in an environment poor in alkalies and Mg. Ralstonite (NaxMgxAl1xF3(H₂O)y), which, unlike oskarssonite, contains Na and Mg as important constituents, dominated in the first-formed fumaroles, but now, 41 years after the eruption of Eldfell, is only a minor phase. The new mineral is named after the Icelandic volcanologist Niels Oskarsson.

Original language	English
Journal	Mineralogical Magazine
Volume	78
Issue number	1
Pages (from-to)	215-222
Number of pages	8
ISSN	0026-461X
DOIs	https://doi.org/10.1180/minmag.2014.078.1.15
Publication status	Published - 2014

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10.1180/minmag.2014.078.1.15

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@article{c0d8b478dda44eeb96fe5df64f3aae03,

title = "Oskarssonite, AlF3, a new fumarolic mineral from Eldfell volcano, Heimaey, Iceland.",

abstract = "The new mineral oskarssonite (IMA2012-088), with ideal formula AlF3, was found in August 2009 at the surface of fumaroles on the Eldfell volcano, Heimaey Island, Iceland (GPS coordinates 63°25'58.9{"}N 20°14'50.3{"}W). It occurs as sub-micron-sized crystals forming a white powder in association with anhydrite, bassanite, gypsum, jarosite, anatase, hematite, opal, ralstonite, jakobssonite and meniaylovite. Chemical analyses by energy-dispersive spectrometry with a scanning electronmicroscope produced the following mean elemental composition: Al, 31.70; F, 58.41; O, 9.22; total 99.33 wt.%. The empirical chemical formula is AlF2.6(OH)0.5 which suggests partial substitution of F by OH. Oskarssonite is rhombohedral, space group R3- c, with ah = 4.9817(4) {\AA} , c = 12.387(1) {\AA} , Vuc = 266.23(5) {\AA} 3, Z = 6. The five strongest lines in the powder diffraction diagram [d in {\AA} (I) (hkl)] are as follows: 3.54 (100) (012), 2.131 (13) (113), 1.771 (20) (024), 1.59 (15) (116), 1.574 (10) (122). Rietveld refinement confirms the identity of oskarssonite with the synthetic rhombohedral form of AlF3. Its structure can be described as a rhombohedral deformation of the idealized cubic perovskitetype octahedral framework of corner-sharing AlF6 groups. Oskarssonite appears in the surface part of the fumaroles where fluorides are abundant. At greater depths (below 10 cm) sulfates dominate among the fumarolic minerals. In accordance with its occurrence, we surmise that oskarssonite forms in the later stages of the fumarolic activity in an environment poor in alkalies and Mg. Ralstonite (NaxMgxAl1xF3(H2O)y), which, unlike oskarssonite, contains Na and Mg as important constituents, dominated in the first-formed fumaroles, but now, 41 years after the eruption of Eldfell, is only a minor phase. The new mineral is named after the Icelandic volcanologist Niels Oskarsson.",

author = "Jacobsen, {Morten J{\o}ln{\ae}s} and {Balic Zunic}, Tonci and Donatella Mitolo and Anna Katerinopoulou and Anna Garavelli and Jakobsson, {Sveinn Peter}",

year = "2014",

doi = "10.1180/minmag.2014.078.1.15",

language = "English",

volume = "78",

pages = "215--222",

journal = "Mineralogical Magazine",

issn = "0026-461X",

publisher = "Mineralogical Society",

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TY - JOUR

T1 - Oskarssonite, AlF3, a new fumarolic mineral from Eldfell volcano, Heimaey, Iceland.

AU - Jacobsen, Morten Jølnæs

AU - Balic Zunic, Tonci

AU - Mitolo, Donatella

AU - Katerinopoulou, Anna

AU - Garavelli, Anna

AU - Jakobsson, Sveinn Peter

PY - 2014

Y1 - 2014

N2 - The new mineral oskarssonite (IMA2012-088), with ideal formula AlF3, was found in August 2009 at the surface of fumaroles on the Eldfell volcano, Heimaey Island, Iceland (GPS coordinates 63°25'58.9"N 20°14'50.3"W). It occurs as sub-micron-sized crystals forming a white powder in association with anhydrite, bassanite, gypsum, jarosite, anatase, hematite, opal, ralstonite, jakobssonite and meniaylovite. Chemical analyses by energy-dispersive spectrometry with a scanning electronmicroscope produced the following mean elemental composition: Al, 31.70; F, 58.41; O, 9.22; total 99.33 wt.%. The empirical chemical formula is AlF2.6(OH)0.5 which suggests partial substitution of F by OH. Oskarssonite is rhombohedral, space group R3- c, with ah = 4.9817(4) Å , c = 12.387(1) Å , Vuc = 266.23(5) Å 3, Z = 6. The five strongest lines in the powder diffraction diagram [d in Å (I) (hkl)] are as follows: 3.54 (100) (012), 2.131 (13) (113), 1.771 (20) (024), 1.59 (15) (116), 1.574 (10) (122). Rietveld refinement confirms the identity of oskarssonite with the synthetic rhombohedral form of AlF3. Its structure can be described as a rhombohedral deformation of the idealized cubic perovskitetype octahedral framework of corner-sharing AlF6 groups. Oskarssonite appears in the surface part of the fumaroles where fluorides are abundant. At greater depths (below 10 cm) sulfates dominate among the fumarolic minerals. In accordance with its occurrence, we surmise that oskarssonite forms in the later stages of the fumarolic activity in an environment poor in alkalies and Mg. Ralstonite (NaxMgxAl1xF3(H2O)y), which, unlike oskarssonite, contains Na and Mg as important constituents, dominated in the first-formed fumaroles, but now, 41 years after the eruption of Eldfell, is only a minor phase. The new mineral is named after the Icelandic volcanologist Niels Oskarsson.

AB - The new mineral oskarssonite (IMA2012-088), with ideal formula AlF3, was found in August 2009 at the surface of fumaroles on the Eldfell volcano, Heimaey Island, Iceland (GPS coordinates 63°25'58.9"N 20°14'50.3"W). It occurs as sub-micron-sized crystals forming a white powder in association with anhydrite, bassanite, gypsum, jarosite, anatase, hematite, opal, ralstonite, jakobssonite and meniaylovite. Chemical analyses by energy-dispersive spectrometry with a scanning electronmicroscope produced the following mean elemental composition: Al, 31.70; F, 58.41; O, 9.22; total 99.33 wt.%. The empirical chemical formula is AlF2.6(OH)0.5 which suggests partial substitution of F by OH. Oskarssonite is rhombohedral, space group R3- c, with ah = 4.9817(4) Å , c = 12.387(1) Å , Vuc = 266.23(5) Å 3, Z = 6. The five strongest lines in the powder diffraction diagram [d in Å (I) (hkl)] are as follows: 3.54 (100) (012), 2.131 (13) (113), 1.771 (20) (024), 1.59 (15) (116), 1.574 (10) (122). Rietveld refinement confirms the identity of oskarssonite with the synthetic rhombohedral form of AlF3. Its structure can be described as a rhombohedral deformation of the idealized cubic perovskitetype octahedral framework of corner-sharing AlF6 groups. Oskarssonite appears in the surface part of the fumaroles where fluorides are abundant. At greater depths (below 10 cm) sulfates dominate among the fumarolic minerals. In accordance with its occurrence, we surmise that oskarssonite forms in the later stages of the fumarolic activity in an environment poor in alkalies and Mg. Ralstonite (NaxMgxAl1xF3(H2O)y), which, unlike oskarssonite, contains Na and Mg as important constituents, dominated in the first-formed fumaroles, but now, 41 years after the eruption of Eldfell, is only a minor phase. The new mineral is named after the Icelandic volcanologist Niels Oskarsson.

U2 - 10.1180/minmag.2014.078.1.15

DO - 10.1180/minmag.2014.078.1.15

M3 - Journal article

SN - 0026-461X

VL - 78

SP - 215

EP - 222

JO - Mineralogical Magazine

JF - Mineralogical Magazine

IS - 1

ER -

Oskarssonite, AlF3, a new fumarolic mineral from Eldfell volcano, Heimaey, Iceland.

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