TY - JOUR
T1 - One-dimensional coordination polymers of [Co3(dpa)4]2+ and [MF6]2- (M = ReIV, ZrIV and SnIV)
AU - Bulicanu, Vladimir
AU - Pedersen, Kasper Steen
AU - Rouzières, Mathieu
AU - Bendix, Jesper
AU - Dechambenoit, Pierre
AU - Clérac, Rodolphe
AU - Hillard, Elizabeth A.
PY - 2015
Y1 - 2015
N2 - One-dimensional coordination polymers of alternating metal-metal bonded trinuclear [Co3(dpa)4]2+ (dpa = the anion of 2,2'-dipyridylamine) building blocks and [ReF6]2- (1), [ZrF6]2- (2) or [SnF6]2- (3) linkers have been self-assembled and crystallographically characterized. Magnetic measurements reveal a significant ferromagnetic coupling (J/kB = +9.9 K) between S = 1/2 {Co36+} and S = 3/2 ReIV magnetic sites through a single, unsupported fluoride bridge in 1.
AB - One-dimensional coordination polymers of alternating metal-metal bonded trinuclear [Co3(dpa)4]2+ (dpa = the anion of 2,2'-dipyridylamine) building blocks and [ReF6]2- (1), [ZrF6]2- (2) or [SnF6]2- (3) linkers have been self-assembled and crystallographically characterized. Magnetic measurements reveal a significant ferromagnetic coupling (J/kB = +9.9 K) between S = 1/2 {Co36+} and S = 3/2 ReIV magnetic sites through a single, unsupported fluoride bridge in 1.
U2 - 10.1039/c5cc06704a
DO - 10.1039/c5cc06704a
M3 - Journal article
C2 - 26490560
SN - 1359-7345
VL - 51
SP - 17748
EP - 17751
JO - Chemical Communications
JF - Chemical Communications
IS - 100
ER -