[Ni(HF2)(3-Clpy)4]BF4 (py = pyridine): evidence for spin exchange along strongly distorted F···H···F- bridges in a one-dimensional polymeric chain

Jamie L. Manson; Adora G. Baldwin; Brian L. Scott; Jesper Bendix; Rico E. Del Sesto; Paul A. Goddard; Yoshimitsu Kohama; Hope E. Tran; Saman Ghannadzadeh; John Singleton; Tom Lancaster; Johannes S. Möller; Stephen J. Blundell; Francis L. Pratt; Vivien S. Zapf; Jinhee Kang; Changhoon Lee; Myung-Hwan Whangbo; Christopher Baines

doi:10.1021/ic300111k

[Ni(HF₂)(3-Clpy)₄]BF₄ (py = pyridine): evidence for spin exchange along strongly distorted F···H···F^- bridges in a one-dimensional polymeric chain

Jamie L. Manson, Adora G. Baldwin, Brian L. Scott, Jesper Bendix, Rico E. Del Sesto, Paul A. Goddard, Yoshimitsu Kohama, Hope E. Tran, Saman Ghannadzadeh, John Singleton, Tom Lancaster, Johannes S. Möller, Stephen J. Blundell, Francis L. Pratt, Vivien S. Zapf, Jinhee Kang, Changhoon Lee, Myung-Hwan Whangbo, Christopher Baines

Department of Chemistry

18 Citations (Scopus)

Abstract

Figure Persented: [Ni(HF ₂)(3-Clpy) ₄]BF ₄ (py = pyridine) is a simple one-dimensional (1D) coordination polymer composed of compressed NiN ₄F ₂ octahedra that form chains with bridging HF ₂ ^- ligands. In spite of significant distortion of the HF ₂ ^- bridge, a quasi-1D antiferromagnetic (AFM) behavior was observed with J _FHF = 4.86 K.

Original language	English
Journal	Inorganic Chemistry
Volume	51
Issue number	14
Pages (from-to)	7520-7528
Number of pages	9
ISSN	0020-1669
DOIs	https://doi.org/10.1021/ic300111k
Publication status	Published - 16 Jul 2012

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Manson, J. L., Baldwin, A. G., Scott, B. L., Bendix, J., Del Sesto, R. E., Goddard, P. A., Kohama, Y., Tran, H. E., Ghannadzadeh, S., Singleton, J., Lancaster, T., Möller, J. S., Blundell, S. J., Pratt, F. L., Zapf, V. S., Kang, J., Lee, C., Whangbo, M-H., & Baines, C. (2012). [Ni(HF₂)(3-Clpy)₄]BF₄ (py = pyridine): evidence for spin exchange along strongly distorted F···H···F^- bridges in a one-dimensional polymeric chain. Inorganic Chemistry, 51(14), 7520-7528. https://doi.org/10.1021/ic300111k

[Ni(HF₂)(3-Clpy)₄]BF₄ (py = pyridine) : evidence for spin exchange along strongly distorted F···H···F^- bridges in a one-dimensional polymeric chain. / Manson, Jamie L.; Baldwin, Adora G.; Scott, Brian L. et al.

In: Inorganic Chemistry, Vol. 51, No. 14, 16.07.2012, p. 7520-7528.

Research output: Contribution to journal › Journal article › Research › peer-review

Manson, JL, Baldwin, AG, Scott, BL, Bendix, J, Del Sesto, RE, Goddard, PA, Kohama, Y, Tran, HE, Ghannadzadeh, S, Singleton, J, Lancaster, T, Möller, JS, Blundell, SJ, Pratt, FL, Zapf, VS, Kang, J, Lee, C, Whangbo, M-H & Baines, C 2012, '[Ni(HF₂)(3-Clpy)₄]BF₄ (py = pyridine): evidence for spin exchange along strongly distorted F···H···F^- bridges in a one-dimensional polymeric chain', Inorganic Chemistry, vol. 51, no. 14, pp. 7520-7528. https://doi.org/10.1021/ic300111k

@article{1827c69e01a747c8a5f8718a638c81da,

title = "[Ni(HF2)(3-Clpy)4]BF4 (py = pyridine): evidence for spin exchange along strongly distorted F···H···F- bridges in a one-dimensional polymeric chain",

abstract = "Figure Persented: [Ni(HF 2)(3-Clpy) 4]BF 4 (py = pyridine) is a simple one-dimensional (1D) coordination polymer composed of compressed NiN 4F 2 octahedra that form chains with bridging HF 2 - ligands. In spite of significant distortion of the HF 2 - bridge, a quasi-1D antiferromagnetic (AFM) behavior was observed with J FHF = 4.86 K.",

author = "Manson, {Jamie L.} and Baldwin, {Adora G.} and Scott, {Brian L.} and Jesper Bendix and {Del Sesto}, {Rico E.} and Goddard, {Paul A.} and Yoshimitsu Kohama and Tran, {Hope E.} and Saman Ghannadzadeh and John Singleton and Tom Lancaster and M{\"o}ller, {Johannes S.} and Blundell, {Stephen J.} and Pratt, {Francis L.} and Zapf, {Vivien S.} and Jinhee Kang and Changhoon Lee and Myung-Hwan Whangbo and Christopher Baines",

year = "2012",

month = jul,

day = "16",

doi = "10.1021/ic300111k",

language = "English",

volume = "51",

pages = "7520--7528",

journal = "Inorganic Chemistry",

issn = "0020-1669",

publisher = "American Chemical Society",

number = "14",

}

TY - JOUR

T1 - [Ni(HF2)(3-Clpy)4]BF4 (py = pyridine)

T2 - evidence for spin exchange along strongly distorted F···H···F- bridges in a one-dimensional polymeric chain

AU - Manson, Jamie L.

AU - Baldwin, Adora G.

AU - Scott, Brian L.

AU - Bendix, Jesper

AU - Del Sesto, Rico E.

AU - Goddard, Paul A.

AU - Kohama, Yoshimitsu

AU - Tran, Hope E.

AU - Ghannadzadeh, Saman

AU - Singleton, John

AU - Lancaster, Tom

AU - Möller, Johannes S.

AU - Blundell, Stephen J.

AU - Pratt, Francis L.

AU - Zapf, Vivien S.

AU - Kang, Jinhee

AU - Lee, Changhoon

AU - Whangbo, Myung-Hwan

AU - Baines, Christopher

PY - 2012/7/16

Y1 - 2012/7/16

N2 - Figure Persented: [Ni(HF 2)(3-Clpy) 4]BF 4 (py = pyridine) is a simple one-dimensional (1D) coordination polymer composed of compressed NiN 4F 2 octahedra that form chains with bridging HF 2 - ligands. In spite of significant distortion of the HF 2 - bridge, a quasi-1D antiferromagnetic (AFM) behavior was observed with J FHF = 4.86 K.

AB - Figure Persented: [Ni(HF 2)(3-Clpy) 4]BF 4 (py = pyridine) is a simple one-dimensional (1D) coordination polymer composed of compressed NiN 4F 2 octahedra that form chains with bridging HF 2 - ligands. In spite of significant distortion of the HF 2 - bridge, a quasi-1D antiferromagnetic (AFM) behavior was observed with J FHF = 4.86 K.

U2 - 10.1021/ic300111k

DO - 10.1021/ic300111k

M3 - Journal article

SN - 0020-1669

VL - 51

SP - 7520

EP - 7528

JO - Inorganic Chemistry

JF - Inorganic Chemistry

IS - 14

ER -

[Ni(HF2)(3-Clpy)4]BF4 (py = pyridine): evidence for spin exchange along strongly distorted F···H···F- bridges in a one-dimensional polymeric chain

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[Ni(HF₂)(3-Clpy)₄]BF₄ (py = pyridine): evidence for spin exchange along strongly distorted F···H···F^- bridges in a one-dimensional polymeric chain