Modification of σ-donor properties of terminal carbide ligands investigated through carbide-iodine adduct formation

Anders Reinholdt; Tom André Jos Vosch; Jesper Bendix

doi:10.1002/anie.201606551

Modification of σ-donor properties of terminal carbide ligands investigated through carbide-iodine adduct formation

Anders Reinholdt, Tom André Jos Vosch, Jesper Bendix

Department of Chemistry

7 Citations (Scopus)

Abstract

The terminal carbide ligands in [(Cy₃P)₂X₂Ru≡C] complexes (X=halide or pseudohalide) coordinate molecular iodine, affording charge-transfer complexes rather than oxidation products. Crystallographic and vibrational spectroscopic data show the perturbations of iodine to vary with the auxiliary ligand sphere on ruthenium, demonstrating the σ-donor properties of carbide complexes to be tunable.

Original language	English
Journal	Angewandte Chemie
Volume	55
Issue number	40
Pages (from-to)	12484-12487
Number of pages	4
ISSN	0044-8249
DOIs	https://doi.org/10.1002/anie.201606551
Publication status	Published - 26 Sept 2016

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title = "Modification of σ-donor properties of terminal carbide ligands investigated through carbide-iodine adduct formation",

abstract = "The terminal carbide ligands in [(Cy3P)2X2Ru≡C] complexes (X=halide or pseudohalide) coordinate molecular iodine, affording charge-transfer complexes rather than oxidation products. Crystallographic and vibrational spectroscopic data show the perturbations of iodine to vary with the auxiliary ligand sphere on ruthenium, demonstrating the σ-donor properties of carbide complexes to be tunable.",

author = "Anders Reinholdt and Vosch, {Tom Andr{\'e} Jos} and Jesper Bendix",

year = "2016",

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doi = "10.1002/anie.201606551",

language = "English",

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T1 - Modification of σ-donor properties of terminal carbide ligands investigated through carbide-iodine adduct formation

AU - Reinholdt, Anders

AU - Vosch, Tom André Jos

AU - Bendix, Jesper

PY - 2016/9/26

Y1 - 2016/9/26

N2 - The terminal carbide ligands in [(Cy3P)2X2Ru≡C] complexes (X=halide or pseudohalide) coordinate molecular iodine, affording charge-transfer complexes rather than oxidation products. Crystallographic and vibrational spectroscopic data show the perturbations of iodine to vary with the auxiliary ligand sphere on ruthenium, demonstrating the σ-donor properties of carbide complexes to be tunable.

AB - The terminal carbide ligands in [(Cy3P)2X2Ru≡C] complexes (X=halide or pseudohalide) coordinate molecular iodine, affording charge-transfer complexes rather than oxidation products. Crystallographic and vibrational spectroscopic data show the perturbations of iodine to vary with the auxiliary ligand sphere on ruthenium, demonstrating the σ-donor properties of carbide complexes to be tunable.

U2 - 10.1002/anie.201606551

DO - 10.1002/anie.201606551

M3 - Letter

C2 - 27612099

SN - 0044-8249

VL - 55

SP - 12484

EP - 12487

JO - Angewandte Chemie

JF - Angewandte Chemie

IS - 40

ER -

Modification of σ-donor properties of terminal carbide ligands investigated through carbide-iodine adduct formation

Abstract

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