Metal–organic frameworks based on pyridyl-tetrazole ligands containing ester or carboxylate pendant arms

Ursula Sheridan; John F.  Gallagher; Morten Jannik Bjerrum; Adrienne Fleming; Fintan Kelleher; John McGinley

doi:10.1016/j.ica.2014.05.028

Metal–organic frameworks based on pyridyl-tetrazole ligands containing ester or carboxylate pendant arms

Ursula Sheridan, John F. Gallagher, Morten Jannik Bjerrum, Adrienne Fleming, Fintan Kelleher, John McGinley

Department of Chemistry

13 Citations (Scopus)

Abstract

The coordination of pyridyl-tetrazole derivatives containing ester substituents, at either the N-1 or N-2 position of the tetrazole ring, with copper(II) chloride results in the formation of either 1:1 or 1:2 copper to ligand complexes, depending on the ligand. However, when the ester functionality is changed to a carboxylate group, the resulting complexation reactions yield metal-organic frameworks. The resulting structures vary dramatically in pore size, depending on both reaction solvents and position of carboxylate group on the tetrazole ring. Despite the presence of sodium cations in the reaction mixtures, no sodium incorporation was ever observed in any of the complexes. This report represents the first attempts at producing copper(II) complexes of the N-1 and N-2 carboxylate derivative of this ligand.

Original language	English
Journal	Inorganica Chimica Acta
Volume	421
Pages (from-to)	200-209
Number of pages	10
ISSN	0020-1693
DOIs	https://doi.org/10.1016/j.ica.2014.05.028
Publication status	Published - 1 Sept 2014

Access to Document

10.1016/j.ica.2014.05.028

Cite this

@article{f51c783fb27a461d847d0a2d6f8ef3fe,

title = "Metal–organic frameworks based on pyridyl-tetrazole ligands containing ester or carboxylate pendant arms",

abstract = "The coordination of pyridyl-tetrazole derivatives containing ester substituents, at either the N-1 or N-2 position of the tetrazole ring, with copper(II) chloride results in the formation of either 1:1 or 1:2 copper to ligand complexes, depending on the ligand. However, when the ester functionality is changed to a carboxylate group, the resulting complexation reactions yield metal-organic frameworks. The resulting structures vary dramatically in pore size, depending on both reaction solvents and position of carboxylate group on the tetrazole ring. Despite the presence of sodium cations in the reaction mixtures, no sodium incorporation was ever observed in any of the complexes. This report represents the first attempts at producing copper(II) complexes of the N-1 and N-2 carboxylate derivative of this ligand.",

author = "Ursula Sheridan and Gallagher, {John F.} and Bjerrum, {Morten Jannik} and Adrienne Fleming and Fintan Kelleher and John McGinley",

year = "2014",

month = sep,

day = "1",

doi = "10.1016/j.ica.2014.05.028",

language = "English",

volume = "421",

pages = "200--209",

journal = "Inorganica Chimica Acta",

issn = "0020-1693",

publisher = "Elsevier",

}

TY - JOUR

T1 - Metal–organic frameworks based on pyridyl-tetrazole ligands containing ester or carboxylate pendant arms

AU - Sheridan, Ursula

AU - Gallagher, John F.

AU - Bjerrum, Morten Jannik

AU - Fleming, Adrienne

AU - Kelleher, Fintan

AU - McGinley, John

PY - 2014/9/1

Y1 - 2014/9/1

N2 - The coordination of pyridyl-tetrazole derivatives containing ester substituents, at either the N-1 or N-2 position of the tetrazole ring, with copper(II) chloride results in the formation of either 1:1 or 1:2 copper to ligand complexes, depending on the ligand. However, when the ester functionality is changed to a carboxylate group, the resulting complexation reactions yield metal-organic frameworks. The resulting structures vary dramatically in pore size, depending on both reaction solvents and position of carboxylate group on the tetrazole ring. Despite the presence of sodium cations in the reaction mixtures, no sodium incorporation was ever observed in any of the complexes. This report represents the first attempts at producing copper(II) complexes of the N-1 and N-2 carboxylate derivative of this ligand.

AB - The coordination of pyridyl-tetrazole derivatives containing ester substituents, at either the N-1 or N-2 position of the tetrazole ring, with copper(II) chloride results in the formation of either 1:1 or 1:2 copper to ligand complexes, depending on the ligand. However, when the ester functionality is changed to a carboxylate group, the resulting complexation reactions yield metal-organic frameworks. The resulting structures vary dramatically in pore size, depending on both reaction solvents and position of carboxylate group on the tetrazole ring. Despite the presence of sodium cations in the reaction mixtures, no sodium incorporation was ever observed in any of the complexes. This report represents the first attempts at producing copper(II) complexes of the N-1 and N-2 carboxylate derivative of this ligand.

U2 - 10.1016/j.ica.2014.05.028

DO - 10.1016/j.ica.2014.05.028

M3 - Journal article

SN - 0020-1693

VL - 421

SP - 200

EP - 209

JO - Inorganica Chimica Acta

JF - Inorganica Chimica Acta

ER -

Metal–organic frameworks based on pyridyl-tetrazole ligands containing ester or carboxylate pendant arms

Abstract

Access to Document

Fingerprint

Cite this