Lanthanide modification of CdSe/ZnS core/shell quantum dots

TY - JOUR

T1 - Lanthanide modification of CdSe/ZnS core/shell quantum dots

AU - Dethlefsen, Johannes Rytter

AU - Mikhailovsky, Alexander A.

AU - Burks, Peter T.

AU - Døssing, Anders Rørbæk

AU - Ford, Peter C.

PY - 2012/11/8

Y1 - 2012/11/8

N2 - Lanthanide-modified CdSe quantum dots (CdSe(Ln) QDs) have been prepared by heating a solution of Cd(oleate) 2, SeO 2, and Ln(bipy)(S 2CNEt 2) 3 (bipy = 2,2′- bipyridine) to 180-190 °C for 10-15 min. The elemental compositions of the resulting CdSe(Ln) cores and CdSe(Ln)/ZnS core/shell QDs show this route to be highly reproducible. The optical absorption spectra of these composite materials are similar to those of the unmodified nanocrystals, but the QD-centered band edge photoluminescence (PL) is partially quenched. The time-gated emission and excitation spectra of the CdSe(Ln) cores display sensitized lanthanide-centered PL upon higher energy excitation of the nanocrystal host but not upon excitation at the lowest energy QD absorption band. Growth of the ZnS shell led to the depletion of about 60% of the lanthanide ions present together with depletion of nearly all of the lanthanide-centered PL. On these bases, we conclude that the lanthanide-centered PL from the CdSe(Ln) cores originates with Ln 3+-related trap states associated with the QD surface.

AB - Lanthanide-modified CdSe quantum dots (CdSe(Ln) QDs) have been prepared by heating a solution of Cd(oleate) 2, SeO 2, and Ln(bipy)(S 2CNEt 2) 3 (bipy = 2,2′- bipyridine) to 180-190 °C for 10-15 min. The elemental compositions of the resulting CdSe(Ln) cores and CdSe(Ln)/ZnS core/shell QDs show this route to be highly reproducible. The optical absorption spectra of these composite materials are similar to those of the unmodified nanocrystals, but the QD-centered band edge photoluminescence (PL) is partially quenched. The time-gated emission and excitation spectra of the CdSe(Ln) cores display sensitized lanthanide-centered PL upon higher energy excitation of the nanocrystal host but not upon excitation at the lowest energy QD absorption band. Growth of the ZnS shell led to the depletion of about 60% of the lanthanide ions present together with depletion of nearly all of the lanthanide-centered PL. On these bases, we conclude that the lanthanide-centered PL from the CdSe(Ln) cores originates with Ln 3+-related trap states associated with the QD surface.

KW - cadmium selenide nanocrystals electronic energy levels semiconductor nanocrystals aquo ions precursor nanoparticles complexes dynamics shell

U2 - 10.1021/jp306915p

DO - 10.1021/jp306915p

M3 - Journal article

SN - 1932-7447

VL - 116

SP - 23713

EP - 23720

JO - The Journal of Physical Chemistry Part C

JF - The Journal of Physical Chemistry Part C

IS - 44

ER -