Kinetics of the reaction of Cl atoms with CHCl3 over the temperature range 253-313 K

Elna Johanna Kristina Nilsson; Janus Hoff; Ole John Nielsen; Matthew Stanley Johnson

Kinetics of the reaction of Cl atoms with CHCl3 over the temperature range 253-313 K

Elna Johanna Kristina Nilsson, Janus Hoff, Ole John Nielsen, Matthew Stanley Johnson

Department of Chemistry

Abstract

The reaction CHCl₃ + Cl → CCl₃ + HCl was studied in the atmospherically relevant temperature range from 253 to 313 K and in 930 mbar of N₂ diluent using the relative rate method. A temperature dependent reaction rate constant, valid in the temperature range 220-330 K, was determined by a fit to the result of the present study and that of Orlando (1999); k = (3.77 ± 0.32) × 10^-12 exp((-1011 ± 24)/T) cm³ molecule^-1 s^-1.

Original language	English
Journal	Chemical Physics Letters
Volume	494
Pages (from-to)	160-162
Number of pages	3
ISSN	0009-2614
Publication status	Published - 19 Jul 2010

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@article{71c791409bbe11df928f000ea68e967b,

title = "Kinetics of the reaction of Cl atoms with CHCl3 over the temperature range 253-313 K",

abstract = "The reaction CHCl3 + Cl → CCl3 + HCl was studied in the atmospherically relevant temperature range from 253 to 313 K and in 930 mbar of N2 diluent using the relative rate method. A temperature dependent reaction rate constant, valid in the temperature range 220-330 K, was determined by a fit to the result of the present study and that of Orlando (1999); k = (3.77 ± 0.32) × 10-12 exp((-1011 ± 24)/T) cm3 molecule-1 s-1.",

author = "Nilsson, {Elna Johanna Kristina} and Janus Hoff and Nielsen, {Ole John} and Johnson, {Matthew Stanley}",

year = "2010",

month = jul,

day = "19",

language = "English",

volume = "494",

pages = "160--162",

journal = "Chemical Physics Letters",

issn = "0009-2614",

publisher = "Elsevier",

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TY - JOUR

T1 - Kinetics of the reaction of Cl atoms with CHCl3 over the temperature range 253-313 K

AU - Nilsson, Elna Johanna Kristina

AU - Hoff, Janus

AU - Nielsen, Ole John

AU - Johnson, Matthew Stanley

PY - 2010/7/19

Y1 - 2010/7/19

N2 - The reaction CHCl3 + Cl → CCl3 + HCl was studied in the atmospherically relevant temperature range from 253 to 313 K and in 930 mbar of N2 diluent using the relative rate method. A temperature dependent reaction rate constant, valid in the temperature range 220-330 K, was determined by a fit to the result of the present study and that of Orlando (1999); k = (3.77 ± 0.32) × 10-12 exp((-1011 ± 24)/T) cm3 molecule-1 s-1.

AB - The reaction CHCl3 + Cl → CCl3 + HCl was studied in the atmospherically relevant temperature range from 253 to 313 K and in 930 mbar of N2 diluent using the relative rate method. A temperature dependent reaction rate constant, valid in the temperature range 220-330 K, was determined by a fit to the result of the present study and that of Orlando (1999); k = (3.77 ± 0.32) × 10-12 exp((-1011 ± 24)/T) cm3 molecule-1 s-1.

M3 - Journal article

SN - 0009-2614

VL - 494

SP - 160

EP - 162

JO - Chemical Physics Letters

JF - Chemical Physics Letters

ER -

Kinetics of the reaction of Cl atoms with CHCl3 over the temperature range 253-313 K

Abstract

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