Kinetics of the gas-phase reactions of chlorine atoms with CH2F2, CH3CCl3 and CF3CFH2 over the temperature range 253 – 551 K

Elna Johanna Kristina Nilsson; Matthew Stanley Johnson; Ole John Nielsen; E. W. Kaiser; T. J. Wallington

Kinetics of the gas-phase reactions of chlorine atoms with CH2F2, CH3CCl3 and CF3CFH2 over the temperature range 253 – 551 K

Elna Johanna Kristina Nilsson, Matthew Stanley Johnson, Ole John Nielsen, E. W. Kaiser, T. J. Wallington

Department of Chemistry

Abstract

Relative rate techniques were used to study the title reactions in 930–1200 mbar
of N2 diluent. The reaction rate coefficients measured in the present work are summarized
by the expressions k(Cl+CH2F2) = 1.19×10-17 T 2 exp(-1023/T ) cm3 molecule-1 s-1 (253–
553 K), k(Cl+CH3CCl3) = 2.41×10-12 exp(-1630/T ) cm3 molecule-1 s-1 (253–313 K), and
k(Cl+CF3CFH2) = 1.27×10-12 exp(-2019/T ) cm3 molecule-1 s-1 (253–313 K). Results are
discussed with respect to the literature data.

Original language	English
Journal	International Journal of Chemical Kinetics
Volume	41
Issue number	6
Pages (from-to)	401 – 406
Number of pages	6
ISSN	0538-8066
Publication status	Published - 5 Oct 2009

Cite this

Kinetics of the gas-phase reactions of chlorine atoms with CH2F2, CH3CCl3 and CF3CFH2 over the temperature range 253 – 551 K. / Nilsson, Elna Johanna Kristina; Johnson, Matthew Stanley ; Nielsen, Ole John et al.

In: International Journal of Chemical Kinetics, Vol. 41, No. 6, 05.10.2009, p. 401 – 406.

Research output: Contribution to journal › Journal article › Research › peer-review

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title = "Kinetics of the gas-phase reactions of chlorine atoms with CH2F2, CH3CCl3 and CF3CFH2 over the temperature range 253 – 551 K",

abstract = "Relative rate techniques were used to study the title reactions in 930–1200 mbarof N2 diluent. The reaction rate coefficients measured in the present work are summarizedby the expressions k(Cl+CH2F2) = 1.19×10-17 T 2 exp(-1023/T ) cm3 molecule-1 s-1 (253–553 K), k(Cl+CH3CCl3) = 2.41×10-12 exp(-1630/T ) cm3 molecule-1 s-1 (253–313 K), andk(Cl+CF3CFH2) = 1.27×10-12 exp(-2019/T ) cm3 molecule-1 s-1 (253–313 K). Results arediscussed with respect to the literature data.",

author = "Nilsson, {Elna Johanna Kristina} and Johnson, {Matthew Stanley} and Nielsen, {Ole John} and Kaiser, {E. W.} and Wallington, {T. J.}",

note = "Paper id:: DOI 10.1002/kin.20398",

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TY - JOUR

T1 - Kinetics of the gas-phase reactions of chlorine atoms with CH2F2, CH3CCl3 and CF3CFH2 over the temperature range 253 – 551 K

AU - Nilsson, Elna Johanna Kristina

AU - Johnson, Matthew Stanley

AU - Nielsen, Ole John

AU - Kaiser, E. W.

AU - Wallington, T. J.

N1 - Paper id:: DOI 10.1002/kin.20398

PY - 2009/10/5

Y1 - 2009/10/5

N2 - Relative rate techniques were used to study the title reactions in 930–1200 mbarof N2 diluent. The reaction rate coefficients measured in the present work are summarizedby the expressions k(Cl+CH2F2) = 1.19×10-17 T 2 exp(-1023/T ) cm3 molecule-1 s-1 (253–553 K), k(Cl+CH3CCl3) = 2.41×10-12 exp(-1630/T ) cm3 molecule-1 s-1 (253–313 K), andk(Cl+CF3CFH2) = 1.27×10-12 exp(-2019/T ) cm3 molecule-1 s-1 (253–313 K). Results arediscussed with respect to the literature data.

AB - Relative rate techniques were used to study the title reactions in 930–1200 mbarof N2 diluent. The reaction rate coefficients measured in the present work are summarizedby the expressions k(Cl+CH2F2) = 1.19×10-17 T 2 exp(-1023/T ) cm3 molecule-1 s-1 (253–553 K), k(Cl+CH3CCl3) = 2.41×10-12 exp(-1630/T ) cm3 molecule-1 s-1 (253–313 K), andk(Cl+CF3CFH2) = 1.27×10-12 exp(-2019/T ) cm3 molecule-1 s-1 (253–313 K). Results arediscussed with respect to the literature data.

M3 - Journal article

SN - 0538-8066

VL - 41

SP - 401

EP - 406

JO - International Journal of Chemical Kinetics

JF - International Journal of Chemical Kinetics

IS - 6

ER -